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低钾含量低温电解质中阴极电解膨胀研究
引用本文:马绍良,李劼,田忠良,李胜银,吕晓军,赖延清,刘业翔.低钾含量低温电解质中阴极电解膨胀研究[J].中南大学学报(自然科学版),2012,43(7):2467-2472.
作者姓名:马绍良  李劼  田忠良  李胜银  吕晓军  赖延清  刘业翔
作者单位:中南大学冶金科学与工程学院,湖南长沙,410083
基金项目:国家高技术研究发展计划(“863”计划)项目
摘    要:以钠冰晶石-钾冰晶石混合体系作为研究对象,测量半石墨质阴极电解膨胀率。研究结果表明:随着AlF3含量的增加,阴极电解膨胀率逐渐降低,且随着AlF3含量的增加,对半石墨质阴极膨胀的影响也加剧了。随着钾含量的增加,半石墨质阴极膨胀率增大,随着钾冰晶石含量的增加,对半石墨质阴极膨胀率的影响是先加剧后减弱。

关 键 词:低钾含量电解质  半石墨质阴极  电解膨胀  低温电解

Cathode expansion of low potassium-sodium cryolite
MA Shao-liang , LI Ye , TIAN Zhong-liang , LI Sheng-yin , LV Xiao-jun , LAI Yan-qing , LIU Ye-xiang.Cathode expansion of low potassium-sodium cryolite[J].Journal of Central South University:Science and Technology,2012,43(7):2467-2472.
Authors:MA Shao-liang  LI Ye  TIAN Zhong-liang  LI Sheng-yin  LV Xiao-jun  LAI Yan-qing  LIU Ye-xiang
Institution:,LAI Yan-qing,TIAN Zhong-liang,LI Sheng-yin (School of Metallurgical Science and Engineering,Central South University,Changsha 410083,China)
Abstract:Semi-graphitic cathode electrolytic measuring swelling was studied based on sodium-potassium cryolite mixed system,the results show that as the content of AlF3 increases,the cathode electrolysis swelling gradually decreases,and as the content of AlF3 increases,semi-graphitic cathode on the impact of inflation is also exacerbated.Semi-graphitic cathode expansion rate increases with the increase of potassium,and the semi-graphitic cathode expansion rate first increases and then decreases with the increase of the content of potassium cryolite.
Keywords:low potassium-sodium cryolite  semi-graphitic cathode  electrolysis expansion  low temperature electrolysis
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