| 10,11-二氢化-7-（4-羟基苯基）-10,10-二甲基苯并[b][1,7]菲咯啉-8（7H,9H,12H）-酮的合成和晶体结构 |
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| 引用本文： | 张梅梅,郑维发.10,11-二氢化-7-（4-羟基苯基）-10,10-二甲基苯并[b][1,7]菲咯啉-8（7H,9H,12H）-酮的合成和晶体结构[J].徐州师范大学学报(自然科学版),2008,26(1):48-51. |
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| 作者姓名： | 张梅梅 郑维发 |
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| 作者单位： | 徐州师范大学,江苏省药用植物生物技术重点实验室,江苏,徐州,221116 |
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| 基金项目： | 江苏省高校自然科学基金 |
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| 摘 要： | 标题化合物C24H22N2O2是由N-（4-羟基苯亚甲基）喹啉-5-胺和5,5-二甲基-1,3-环己二酮在氯化三乙基苄基铵（TEBAC）催化下以水作溶剂反应而得.结构通过单晶X射线衍射分析确定,其晶体属于正交晶系,空间群c2221,a=1.6558（2）,b=1.6547（2）,c=2.8975（3）nm,Mr=370.44,V=7.9387（16）nm^3,Dc=1.240g/cm^3,Z=16,μ（MoKα）=0.7900cm-1,F（000）=3136.晶体结构用直接法解出,使用全矩阵最小二乘法对原子参数进行修正,最后的偏离因子R=0.0380,Rw=0.0862.
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| 关 键 词： | 菲咯啉 氯化三乙基苄基铵 合成 晶体结构 |
| 文章编号： | 1007-6573(2008)01-0048-04 |
| 修稿时间： | 2007年9月13日 |
Synthesis and Crystal Structure of 10,11-Dihydro-7-(4-hydroxyphenyl)-10,10-dimethylbenzo[b][1,7]phenanthroline-8(7H,9H,12H)-one |
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| ZHANG Mei-mei,ZHENG Wei-fa.Synthesis and Crystal Structure of 10,11-Dihydro-7-(4-hydroxyphenyl)-10,10-dimethylbenzo[b][1,7]phenanthroline-8(7H,9H,12H)-one[J].Journal of Xuzhou Normal University(Natural Science Edition),2008,26(1):48-51. |
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| Authors: | ZHANG Mei-mei ZHENG Wei-fa |
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| Institution: | ZHANG Mei-mei , ZHENG Wei- fa (Key Laboratory of Bioteehnology on Medical Plant, Xuzhou Normal University, Xuzhou, Jiangsu, 221116, China) |
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| Abstract: | The title compound C24 H22 N2O2 has been synthesized by the reaction of N-arylidenenaphthalen-2-amine with 5,5-dimethyl-1,3-cyclohexadione water catalyzed by triethylbenzylammonium chloride（TEBAC）. Its structure was determined by single crystal X-ray diffraction. The crystal is orthorhombic,space group c 2221 with a=1.655 8（2）, b=1.654 7（2）, c=2. 897 5（3） nm, Mr= 370.44, V=7. 938 7（16） nm^3, Dc=1.240 g/cm^3 , Z=16, μ（Mo Kα）=0. 790 0 cm^-1 ,F（000）=3 136. The structure was solved by direct methods and refined by full-matrix least-squares method to the final R=0. 038 0,Rw=0. 086 2. |
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| Keywords: | phenanthroline triethylbenzylammonium chloride synthesis crystal structure |
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