| 水杨醛希夫碱功能化介孔硅基吸附剂制备及其对水体中Cu(Ⅱ)离子的吸附性能研究 |
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| 引用本文： | 黄进,徐继明.水杨醛希夫碱功能化介孔硅基吸附剂制备及其对水体中Cu(Ⅱ)离子的吸附性能研究[J].淮阴师范学院学报(自然科学版),2013(4):304-310. |
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| 作者姓名： | 黄进 徐继明 |
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| 作者单位： | 淮阴师范学院化学化工学院,江苏省低维材料化学重点建设实验室,江苏淮安223300 |
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| 基金项目： | 基金项目：江苏省高校自然科学研究重大项目（11KJA150004）;江苏省低维材料化学重点建设实验室开放课题（JSKC12123） |
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| 摘 要： | 采用后嫁接法制备了水杨醛希夫碱功能化介孔硅基吸附材料SA-SBA-15,对Cu(II)离子的饱和吸附量为60.0 mg/g,最佳溶液pH值为5.动力学研究表明,合成的SA-SBA-15对Cu(II)离子的吸附40 min达到平衡.吸附Cu(II)离子后形成的Cu-SA-SBA-15具有良好的杀菌性能,对大肠杆菌的最小抑菌浓度为160μg/mL,对金黄色葡萄球菌的最小抑菌浓度为120μg/mL.
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| 关 键 词： | SBA-15 希夫碱 铜离子 吸附 抗菌 |
Salicylidene Schiff Base Assembled with Mesoporous Silica SBA-15 for Cu（II） Removal in Aqueous Media |
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| HUANG Jin,XU Ji-ming.Salicylidene Schiff Base Assembled with Mesoporous Silica SBA-15 for Cu（II） Removal in Aqueous Media[J].Journal of Huaiyin Teachers College(Natrual Science Edition),2013(4):304-310. |
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| Authors: | HUANG Jin XU Ji-ming |
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| Institution: | (Jiangsu Province Key Laboratory for Chemistry of Low-Dimensional Materials, School of Chemistry and Chemical Engineering, Huaiyin Normal University, Huaian Jiangsu 223300, China) |
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| Abstract: | Salicylidene Schiff base-functionalized SBA-15 mesoporous silica is prepared ,characterized and used as an adsorbent for heavy metal ion ,Cu（II） .By post-grafting ,the organic-inorganic hybrid mesoporous materials have been synthesized by tetraethoxysilane （TEOS ） with 3-aminopropyltrimethoxy-silane （APTES ） and salicylalde-hyde in sequence .The functionalized mesoporous materials are characterized by means of XRD ,FT-IR ,TEM and N2 adsorption-desorption analysis .The result indicates that ,after sequent chemical modifications of aminopropyl and schiff base ,the primary hexagonally ordered mesoporous structure of SBA-15 is not affected ,exhibits the excellent adsorption capacity .The removal rate of copric ion in aqueous media is high and the adsorbent can be regenerated by EDTA treatments without changing its properties .Meanwhile ,Cu-SBA-15 antibacterial agent was shown to be an effective bactericide against Bacillus coli and Staphylococcus aureus ,indicating that it has good antibacterial effect . |
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| Keywords: | schiff base copric ion adsorption antibacterial activity |
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