| [Mn(mnt)(phen-5,6-dione)]配合物的光敏性研究 |
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| 引用本文： | 潘庆才,沈红旗,闫凤美,李伟,彭正合. [Mn(mnt)(phen-5,6-dione)]配合物的光敏性研究[J]. 河南科学, 2008, 26(2): 166-168 |
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| 作者姓名： | 潘庆才 沈红旗 闫凤美 李伟 彭正合 |
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| 作者单位： | 1. 黄淮学院,化学化工系,驻马店,463000
2. 武汉大学,化学与分子科学学院,武汉,430072 |
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| 基金项目： | 国家自然科学基金 , 河南省教育厅自然科学基金 |
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| 摘 要： | 测量了标题配合物[Mn(mnt)(phen-5,6--dione)](mnt2-:1,2-二氰基乙烯-1,2-二硫醇离子.phen-5,6-dione:-1,10-菲咯啉-5,6-二酮)在二甲基亚砜(DMSO)、二甲基甲酰胺(DMF)、丙酮(CH3COCH3)等溶剂中的电子吸收光谱和电子发射光谱特性,报道了掺杂有标题配合物[Mn(mnt)(phen-5,6-dione)]的CdS-PVA复合膜的暗态导电性和光电导性,研究了[Mn(mnt)(phen-5,6-dione)]对CdS的光敏化作用与其电子光谱间的关系.
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| 关 键 词： | 二硫纶 菲咯啉二酮 锰 配合物 光敏性 |
| 文章编号： | 1004-3918（2008）02-0166-03 |
| 收稿时间： | 2007-10-18 |
| 修稿时间： | 2007-10-18 |
Study on the Photoconductivity and Photosensitivity of [Mn(mnt)(phen-5,6-dione)] |
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| Pan Qingcai,Shen Hongqi,Yan Fengmei,Li Wei,Peng Zhenghe. Study on the Photoconductivity and Photosensitivity of [Mn(mnt)(phen-5,6-dione)][J]. Henan Science, 2008, 26(2): 166-168 |
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| Authors: | Pan Qingcai Shen Hongqi Yan Fengmei Li Wei Peng Zhenghe |
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| Affiliation: | 1.Department of Chemistry and Chemical Engineering;Huanghuai University;Zhumadian 463000;China;2.College of Chemistry and Molecular Science;Wuhan University;Wuhan 430072;China |
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| Abstract: | The electronic absorption spectra and emission spectra of complex Mn(mnt)(phen-5,6-dione)(mnt=mnt2-,1,2-dicyano-1,2-ethylenedithiolate or maleonitriledithiolate.Phen-5,6-dione=phen-5,6-dione,1,10-phenan throline-5,6-dione)in DMSO,DMF and CH3COCH3 were measured.The dark conductivity and photoco-nductivity of CdS doped with Mn(mnt)(phen-5,6-dione) were reported.The correlation betwee photosensitization of complex Mn(mnt)(phen-5,6-dione)to CdS and their electronic spectra were studied. |
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| Keywords: | dithiolate phen-5,6-dione manganese complex photosensitivity |
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