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Tungstate ion resonance Rayleigh scattering method for determination of basic triphenylmethane dyes
Authors:LiHong Yu  ZhongFang Liu  XiaoLi Hu  Ling Kong  ShaoPu Liu
Institution:School of Chemistry and Chemical Engineering; Key Laboratory on Luminescence and Real-Time Analysis, Ministry of Education, Southwest University, Chongqing 400715, China
Abstract:In a pH 4.2-6.0 HAc-NaAc buffer medium,the resonance Rayleigh scattering intensities of separate basic triphenylmethane dyes,such as methyl violet (MV),ethyl violet (EV),crystal violet (CV),methyl green (MeG),iodine green (IG),malachite green (MG),light green (LG),and tungstate ion solution,are very weak,but when these cationic dyes react with the tungstate ion (WO 42-) to form ion-association complexes,their RRS are enhanced sharply and new RRS spectra appear.The reaction products of methyl violet,ethyl vi...
Keywords:basic triphenylmethane dyes  malachite green  leuco malachite green  leuco crystal violet  tungstate ion  resonance Rayleigh scattering  
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