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PAN基中空活性炭纤维的制备及性能研究
引用本文:付正芳,孙俊芬,王庆瑞. PAN基中空活性炭纤维的制备及性能研究[J]. 东华大学学报(自然科学版), 2006, 32(4): 128-132
作者姓名:付正芳  孙俊芬  王庆瑞
作者单位:东华大学纤维材料改性国家重点实验室,上海,200051
摘    要:讨论了用聚丙烯腈(PAN)基中空纤维为原料,采用KOH活化法制备中空活性炭纤维(ACHF)的活化过程。考察不同KOH质量浓度对中空活性炭纤维性能的影响。测量了比表面积和得率,孔径分布,用碘吸附值、亚甲基兰吸附值测定了中空活性炭纤维的吸附性能,用SEM观察了其表面结构。结果显示,KOH活化法得到的中空活性炭纤维具有窄的孔径分布,较大的比表面积和较高的得率。

关 键 词:PAN基中空活性炭纤维  制备  KOH活化法  孔径分布
修稿时间:2005-01-21

Study on the Preparation and Properties of PAN-ACHF
FU Zheng-fang,SUN Jun-fen,WANG Qing-rui. Study on the Preparation and Properties of PAN-ACHF[J]. Journal of Donghua University, 2006, 32(4): 128-132
Authors:FU Zheng-fang  SUN Jun-fen  WANG Qing-rui
Abstract:Activated carbon hollow fibers(ACHF) were prepared from polyacrylonitrile(PAN) hollow fiber through oxidation,carbonization and KOH activation.The effects of the KOH concentration on the properties of the resulting PAN based ACHF(PAN-ACHF) were studied.The specific surface area,pore size and yield ratio have been measured.Iodine and Methylene blue adsorption were used to study the adsorption capacity of ACHF.The porous structure of PAN-ACHF was studied by means of scanning electron microscopy(SEM).The results show that PAN-ACHF has larger specific surface area,narrow pore size distribution and high yield ratio.
Keywords:polyacrylonitrile activated carbon hollow fiber  preparation  KOH activation method  pore size distribution
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