| 不同掺杂态聚苯胺的合成及其红外光谱的研究 |
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| 引用本文： | 杨渊,刘小珍,宋玲玲,谢以璋,俞亚钧.不同掺杂态聚苯胺的合成及其红外光谱的研究[J].上海应用技术学院学报,2007,7(1):18-22. |
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| 作者姓名： | 杨渊 刘小珍 宋玲玲 谢以璋 俞亚钧 |
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| 作者单位： | 上海水产大学食品学院，上海应用技术学院化学工程系，江西赣南师范学院，上海应用技术学院化学工程系，上海应用技术学院化学工程系 上海200090，上海应用技术学院化学工程系，上海200235，上海200235，江西赣州341000，上海200235，上海200235 |
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| 基金项目： | 上海市学科建设项目;上海市科委科技计划 |
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| 摘 要： | 以十二烷基苯磺酸(DBSA)和樟脑磺酸(CSA)作为掺杂剂,采用乳液聚合法和研磨法,合成了DBSA掺杂聚苯胺、CSA和DBSA共掺杂聚苯胺,探讨了合成条件对掺杂聚苯胺导电性能的影响,并研究了掺杂聚苯胺的红外光谱。DBSA掺杂聚苯胺、CSA和DBSA共掺杂聚苯胺的电导率分别为0.274 S/cm和1.210 S/cm。在DBSA掺杂聚苯胺中再掺杂CSA,可提高聚苯胺的电导率。
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| 关 键 词： | 聚苯胺 掺杂 电导率 导电高分子 红外光谱 |
| 文章编号： | 1671-7333（2007）01-0018-05 |
| 修稿时间： | 2007-01-20 |
A Study on Synthesis and FT-IR Characterization of Doped Polyaniline |
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| YANG Yuan,LIU Xiao-zhen,SONG Ling-ling,XIE Yi-zhang,YU Ya-jun.A Study on Synthesis and FT-IR Characterization of Doped Polyaniline[J].Journal of Shanghai Institute of Technology: Natural Science,2007,7(1):18-22. |
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| Authors: | YANG Yuan LIU Xiao-zhen SONG Ling-ling XIE Yi-zhang YU Ya-jun |
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| Institution: | 1. College of Food Science and Technology, Shanghai Fisheries University, Shanghai 200090, China; 2. Department of Chemical Engineering, Shanghai Institute of Technology, Shanghai 200235, China; 3. GanNan Normal University, Ganzhou, Jiangxi 341000, China |
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| Abstract: | Dodecylbenzenesulphonic acid,DBSA and camphorsulfonic acid(CSA) were used as dopant respectively in preparation conductive polyaniline by emulsion polymerization and grinding doping.Effects on synthetic condition to conductivity of polyailine and the Fourier transform infrared(FTIR) spectra of doped polyaniline were studied.The conductivity of Polyaniline doped with DBSA,DBSA and CSA were 0.274 S/cm and 1.210 S/cm respectively.It showed that the conductance of Polyaniline doped DBSA could be enhanced by second doping with CSA. |
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| Keywords: | Polyaniline doping conductivity conductive high polymer FTIR spectra |
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