首页 | 本学科首页   官方微博 | 高级检索  
     检索      


Ten reasons why a thermalized system cannot be described by a many-particle wave function
Institution:1. University of Appl. Sciences, 40474 Düsseldorf, Germany;2. Inst. Physics, Carl-von-Ossietzky-Univ., 26111 Oldenburg, Germany;3. Inst. Mathematics, Hebrew University of Jerusalem, Israel;4. Jerusalem College of Technology, Israel;5. Inst. Theor. Physics, University of Cologne, 50923 Köln, Germany;6. Department of Physics & Astron., University of Missouri, Columbia, MO 65211, USA;1. Carl von Ossietzky University of Oldenburg, Center of Interface Science (CIS), Department of Pure and Applied Chemistry, D-26111 Oldenburg, Germany;2. Department of Physical Chemistry and Electrochemistry, Faculty of Chemistry, Jagiellonian University, ul. R. Ingardena 3, 30-060 Krakow, Poland;3. Structure et Réactivité des Systèmes Moléculaires Complexes, UMR CNRS 7565, Faculté des Sciences et Techniques, Université de Lorraine, 54506 Vand?uvre-lès-Nancy, France;1. Universitätsklinikum Hamburg-Eppendorf, Institut und Poliklinik für Medizinische Psychologie, Hamburg, Germany;2. Universität Oldenburg, Department für Versorgungsforschung, Oldenburg, Germany;3. Universitätsklinikum Hamburg-Eppendorf, Klinik und Poliklinik für Psychiatrie und Psychotherapie, Hamburg, Germany;4. Universität Potsdam, Abteilung für Klinische Psychologie und Psychotherapie, Potsdam, Germany
Abstract:It is widely believed that the underlying reality behind statistical mechanics is a deterministic and unitary time evolution of a many-particle wave function, even though this is in conflict with the irreversible, stochastic nature of statistical mechanics. The usual attempts to resolve this conflict for instance by appealing to decoherence or eigenstate thermalization are riddled with problems. This paper considers theoretical physics of thermalized systems as it is done in practice and shows that all approaches to thermalized systems presuppose in some form limits to linear superposition and deterministic time evolution. These considerations include, among others, the classical limit, extensivity, the concepts of entropy and equilibrium, and symmetry breaking in phase transitions and quantum measurement. As a conclusion, the paper suggests that the irreversibility and stochasticity of statistical mechanics should be taken as a real property of nature. It follows that a gas of a macroscopic number N of atoms in thermal equilibrium is best represented by a collection of N wave packets of a size of the order of the thermal de Broglie wave length, which behave quantum mechanically below this scale but classically sufficiently far beyond this scale. In particular, these wave packets must localize again after scattering events, which requires stochasticity and indicates a connection to the measurement process.
Keywords:
本文献已被 ScienceDirect 等数据库收录!
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号