首页 | 本学科首页   官方微博 | 高级检索  
     

预炭化过程中升温速率对碳纤维结构与性能的影响
引用本文:刘杰,程志涛,连峰,马兆昆,黄翔宇. 预炭化过程中升温速率对碳纤维结构与性能的影响[J]. 北京化工大学学报(自然科学版), 2011, 38(4): 68-73
作者姓名:刘杰  程志涛  连峰  马兆昆  黄翔宇
作者单位:北京化工大学 碳纤维及功能高分子教育部重点实验室,北京,100029;上海石油化工股份有限公司,上海,200540
基金项目:国家“863”计划,国家自然科学基金
摘    要:借助13C核磁共振波谱(13C-NMR),X射线衍射(XRD),拉曼光谱(Raman)等表征手段,研究了预炭化过程中聚丙烯腈基热氧稳定化纤维的热化学反应以及微观结构的变化,且重点研究了预炭化过程(400~800 ℃)升温速率对纤维热应力、结构、力学性能的影响。结果表明:随着预炭化升温速率的提高,纤维类石墨层间距 d002 呈现出先减小后增大,晶区堆叠厚度 Lc 呈现出先增大后减小的的趋势;与之相对应的纤维拉伸强度和拉伸模量则呈现出先增大后减小的变化;当升温速率达到132 ℃/min时, d002 和 Lc 分别出现最小值和最大值,此时所得碳纤维的力学性能最高。

关 键 词:碳纤维  聚丙烯腈  预炭化  升温速率  性能
收稿时间:2011-03-13

Effect of heating rate-induced microstructure changes during pre-carbonization on the mechanical properties of carbon fibers
LIU Jie,CHENG ZhiTao,LIAN Feng,MA ZhaoKun,HUANG XiangYu. Effect of heating rate-induced microstructure changes during pre-carbonization on the mechanical properties of carbon fibers[J]. Journal of Beijing University of Chemical Technology, 2011, 38(4): 68-73
Authors:LIU Jie  CHENG ZhiTao  LIAN Feng  MA ZhaoKun  HUANG XiangYu
Affiliation:1Key Laboratory of Carbon Fiber and Functional Polymers, Ministry of Education, Beijing University of Chemical Technology, Beijing 100029; 2Shanghai Petrochemical Co., LTD, Shanghai 200540, China
Abstract:The chemical reactions and microstructure evolution occurring during pre-carbonization(400-800 ℃) of thermally stabilized polyacrylonitrile(PAN) fibers have been investigated by Raman spectroscopy,XRD and 13C-NMR,with a focus on the effects of varying the heating rate during the pre-carbonization process on the morphological structures,thermal stress and mechanical properties of the pre-carbonized fibers and carbon fibers.With increasing heating rate during pre-carbonization,the crystallite size(Lc) in both pre-carbonized fibers and carbon fibers initially increased and then decreased,whilst the interlayer spacing(d002) showed the opposite trend.The mechanical properties of the carbon fibers showed a strong dependence on the differences in structural evolution caused by variation in heating rate during pre-carbonization.When the heating rate was 132 ℃/min,the value of Lc was a maximum and d002 was a minimum,which resulted in carbon fibers having the optimum mechanical properties.
Keywords:carbon fiber  polyacrylonitrile  pre-carbonization  heating rate  properties
本文献已被 CNKI 万方数据 等数据库收录!
点击此处可从《北京化工大学学报(自然科学版)》浏览原始摘要信息
点击此处可从《北京化工大学学报(自然科学版)》下载全文
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号