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金属有机骨架衍生双金属氧化物的锂离性能
引用本文:张燕锋,蔡昌,谈馨怡,孙炜伟. 金属有机骨架衍生双金属氧化物的锂离性能[J]. 上海大学学报(自然科学版), 2021, 27(1): 125-132. DOI: 10.12066/j.issn.1007-2861.2072
作者姓名:张燕锋  蔡昌  谈馨怡  孙炜伟
作者单位:上海大学环境与化学工程学院,上海200444
基金项目:生态纺织教育部重点实验室开放课题
摘    要:通过一步微波法设计合成了含有Co和Zn的双金属有机骨架结构,并在氧气氛围下500℃煅烧衍生获得由纳米粒子组装的Co-Zn-O双金属氧化物微米棒材料.衍生材料延承了双金属有机骨架前驱体的微米棒形貌和多孔特性,具有两种不同的金属组分之间的协同储锂作用.Co-Zn-O双金属氧化物作为锂离子电池负极材料时展现了较高的比容量与循...

关 键 词:金属有机骨架  双金属氧化物  锂离子电池  负极材料
收稿时间:2018-05-11

Mixed-metal oxide derived from bimetal-organic frameworks for performance lithium-ion batteries
ZHANG Yanfeng,CAI Chang,TAN Xinyi,SUN Weiwei. Mixed-metal oxide derived from bimetal-organic frameworks for performance lithium-ion batteries[J]. Journal of Shanghai University(Natural Science), 2021, 27(1): 125-132. DOI: 10.12066/j.issn.1007-2861.2072
Authors:ZHANG Yanfeng  CAI Chang  TAN Xinyi  SUN Weiwei
Affiliation:School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China
Abstract:Co/Zn bimetal organic framework precursor (Co/Zn-MOF-74) has been obtained by using the one-step facile microwave-assisted solvothermal method. By calcining the Co/Zn-MOF-74 at 500 ${^circ}$C under air, the mesoporous mixed-metallic Co-Zn-O microrod can be obtained. When applied as the anode materials for lithium-ion batteries, the Co-Zn-O electrode exhibits good electrochemical properties (reversible capacity of 1 137 mA$cdot$h$cdot$g-1 after 100 cycles), which could be attributed to its mesoporous nanostructure along with the synergistic effects between two different metal species.
Keywords:metal-organic frameworks  mixed-metal oxide  lithium-ion batteries  anode material  
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