| 桥式双核Cu(Ⅱ)配合物的合成与表征 |
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| 引用本文： | 王冬梅,杨瑞娜.桥式双核Cu(Ⅱ)配合物的合成与表征[J].河南师范大学学报(自然科学版),1992,20(4):75-78. |
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| 作者姓名： | 王冬梅 杨瑞娜 |
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| 作者单位： | 河南省化学研究所 450003 |
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| 基金项目： | 配位化学重点实验室基金，国家自然科学基金 |
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| 摘 要： | 本文合成了一组草酸根桥联的双核铜配合物Cu_2C_2O_4(Phen)_2Y_2],Phen代表1、10-邻菲中啰啉,Y为不同的阴离子)。通过元素分析、IR、X-射线粉末衍射、顺磁共振对其进行表征并推测其结构。研究了它们的摩尔电导、热重等方面的性质。
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| 关 键 词： | 双核配合物 草酸根桥 邻菲啰啉 |
SYNTHESIS AND CHARACTERIZATION OF DICOPPER[Cu(Ⅱ)]COMPLEXES THROUGH OXALATO BRIDGE |
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| Wang Dongmei,Yang Ruina,Xi Zhengfeng,Xue Baoyu,Jin Douman Henan Institute of Chemistry.SYNTHESIS AND CHARACTERIZATION OF DICOPPER[Cu(Ⅱ)]COMPLEXES THROUGH OXALATO BRIDGE[J].Journal of Henan Normal University(Natural Science),1992,20(4):75-78. |
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| Authors: | Wang Dongmei Yang Ruina Xi Zhengfeng Xue Baoyu Jin Douman Henan Institute of Chemistry |
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| Institution: | Wang Dongmei;Yang Ruina;Xi Zhengfeng;Xue Baoyu;Jin Douman Henan Institute of Chemistry |
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| Abstract: | Dicopper Cu(Ⅱ)complexes through oxalato bridge have been synthesized.The chemicalcomposition of these complexes was ascertained by elementary and chemical analysis.IR,X-raydiffraction and ESR.Characters of molar conductivities and TG were also studied. |
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| Keywords: | bridge dicopper complexes oxalato bridge phenanthroline |
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