Oxidation behavior of the Fe-36Al-0.09C-0.09B-0.04Zr alloy at 1250°C |
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Authors: | Jun-you Liu Feng Li Jie Liu Yi Zhang Jin-cheng Jiang Dun-xu Zou |
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Institution: | (1) College of Applied Chemistry, Shenyang University of Chemical Technology, Shenyang, 110142, China;(2) Department of Applied Chemistry, School of Engineering, University of Toyama, Gofuku 3190, Toyama 930-8555, Japan |
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Abstract: | To explore and study the Fe-Al system alloy presenting exceptional oxidation resistance at high temperature, the Fe-36Al-0.09C-0.09B-0.04Zr
alloy was designed and developed. The microstructure and hardness of the backing at 1250°C were analyzed and measured. Thermodynamics
and kinetics of the oxidation behavior were also analyzed by X-ray diffraction, scanning electron microscopy, and energy-dispersive
X-ray spectroscopy techniques. The results show that the microstructure of the Fe-36Al-0.09C-0.09B-0.04Zr alloy is FeAl phase
at ambient temperature and is stable at 1250°C. It displays the excellent property of oxidation resistance because the oxide
film has only the Al2O3 layer, and its oxidation kinetics curve obeys the parabolic law at 1250°C. The oxidation mechanism at 1250°C is presumed
that in the early oxidation period, the alloy oxidizes to form a large number of Al2O3 and a little Fe2O3, then, the enrichment of Al caused by Fe oxidization combines with O to form Al2O3. |
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