| Ni、Co、Mn（Salen）／MCM-41的制备及其催化性能的研究 |
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| 引用本文： | 郭蕊,李树晓,赵振波.Ni、Co、Mn（Salen）／MCM-41的制备及其催化性能的研究[J].应用科技,2009,36(8):4-7. |
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| 作者姓名： | 郭蕊 李树晓 赵振波 |
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| 作者单位： | 长春工业大学化学与生命科学学院,吉林长春,130012 |
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| 基金项目： | 教育部留学回国人员科研启动资金资助项目，吉林省教育厅科技发展计划基金资助项目 |
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| 摘 要： | 直接合成法制备了NH2-MCM-41，进而负载Ni、Co、Mn（Salen）配合物制备了催化剂．采用傅里叶变换红外光谱（FT-IR）、X射线衍射（XRD）对催化剂进行了表征．将这些催化剂用于以H2O2为氧化剂的环己烯环氧化反应，结果表明：与Ni（Salen）／MCM-41和Co（Salen）／MCM41相比，Mn（Salen）／MCM41具有较高的反应活性．以Mn（Salen）／MCM41为催化剂，获得了优化的反应条件：在n（C6H10）／n（H2O2）=3、20mL乙腈为溶剂、反应时间4h的条件下，环己烯转化率为8．0％，选择性为47．5％．
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| 关 键 词： | 过渡金属 Salen配合物 介孔材料 环氧化 H2O2 |
Synthesis and catalytic performance of Ni, Co and Mn (Salen) /MCM-41 |
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| GUO Rui,LI Shu-xiao,ZHAO Zhen-bo.Synthesis and catalytic performance of Ni, Co and Mn (Salen) /MCM-41[J].Applied Science and Technology,2009,36(8):4-7. |
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| Authors: | GUO Rui LI Shu-xiao ZHAO Zhen-bo |
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| Institution: | (School of Chemistry and Life Science, Changchun University of Technology, Changchun 130012, China) |
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| Abstract: | Functional materials Ni, Co and Mn （salen） had been successfully incorporated into mesoporous NH2- MCM-41 which was synthesized by one-pot methods. These materials were characterized by FT-IR and XRD and then used as catalysts in the epoxidation of cyclohexene. The reaction used aqueous hydrogen peroxide as oxidation agent. Compared with Ni（Salen）/MCM-41 and Co （Salen）/MCM-41, Mn（Salen）/MCM-41 showed excellent catalytic activity. The effects of reaction conditions on the oxidation reaction catalyzed by Mn（Salen）/MCM-41 were investigated to obtain optimal ones ： choosing 20ml acetonitrile as solvent, reaction time for 4h, then the conversion rate of cyclohexene was 8% and the selective probability of cyclohexene epoxide was 47.5% . |
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| Keywords: | H2O2 |
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