| C60双氮杂衍生物的合成与结构分析 |
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| 引用本文： | 陈小莲,唐光诗,李江波.C60双氮杂衍生物的合成与结构分析[J].北京化工大学学报(自然科学版),2003,30(1):73-76. |
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| 作者姓名： | 陈小莲 唐光诗 李江波 |
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| 作者单位： | 北京化工大学可控化学反应科学与技术基础教育部重点实验室,北京,100029 |
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| 基金项目： | 国家自然科学基金;59902001; |
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| 摘 要： | 利用具有二个叠氮基团的化合物A与C60反应，以氯苯为反应溶剂，回流5h后，溶液经柱色谱分离(硅胶，V甲苯/V环己烷=1)得到了C60双氮杂衍生物B。用紫外、红外、质谱、氢核磁等对衍生物B作了初步表征，并结合半经验AM1程序所做的能量计算，讨论并初步确定了衍生物B最有可能是两个极性一致、结构为双6,5]开环氮杂桥轮烯结构化合物异构体的混合物 。
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| 关 键 词： | C60衍生物 氮杂桥 合成 C60衍生物 氮杂桥 合成 |
| 修稿时间： | 2002年5月17日 |
Design and synthesis of C60 double-aza-bridge derivative |
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| CHEN Xiao-lian,TANG Guang-shi,LI Jiang-bo.Design and synthesis of C60 double-aza-bridge derivative[J].Journal of Beijing University of Chemical Technology,2003,30(1):73-76. |
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| Authors: | CHEN Xiao-lian TANG Guang-shi LI Jiang-bo |
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| Institution: | The Key Laboratory of Science and Technology of Controllable Chemical Reactions; Ministry of Education; Beijing University of Chemical Technology; Beijing; China |
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| Abstract: | A solution of C60 200.0mg(0.278 mmol) and 2-nitro-2-methyl-1,3-diazidopropane(A) 61.7 mg (0.33 mmol) in chlorobenzol(240 mL) was refluxed for 5 h and gave a red solution, which was purified by column chromatography on silica gel, using cyclohexane-toluene(1∶1,volume ratio) as eluant and then C 60 double-aza-bridge derivative(B) 21.6mg and 27% yield(based on the consumption of C 60) could be obtained. It was characterized by UV-vis, FTIR, MS and 1H-NMR spectrum, and its structure was supported by the ball-stick model and the calculation of semi-experimental AM1 program. The product may be a mixture of two isomers of double open-aza-bridge structure. |
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| Keywords: | C_ 60 derivative double-aza-bridge synthesis |
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