| 2：2型过氧钨酸盐的制备,结构和性质研究 |
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| 引用本文： | 石晓波 李春根. 2：2型过氧钨酸盐的制备,结构和性质研究[J]. 江西师范大学学报(自然科学版), 1994, 18(1): 25-28 |
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| 作者姓名： | 石晓波 李春根 |
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| 作者单位： | 江西师大化学系 南昌330027(石晓波，李春根，林秉发)，江西师大化学系 南昌330027(巫生华) |
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| 摘 要： | 在H_2O_2溶液中.通过活性粉状白钨酸的解聚制备了二个O_2~(2-):W为2:2型的新的过氧钨酸盐:K_2W_2O_s(O_2)_2·4H_2O(1)和(E_(t4)N~-)_2W_2O_5(O_2)_2·2H_2O(2).用IR、UV和XRD对二个过氧化物进行了表征,并推断了过氧钨酸阴离子的可能结构.
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| 关 键 词： | 过氧钨酸盐 制备 WPTA 钨酸 |
Preparation and Structure and Properties of Diperoxyditungstates |
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| Shi Xiaobo Li Chungen Lin Bingfa Wu Shenghua. Preparation and Structure and Properties of Diperoxyditungstates[J]. Journal of Jiangxi Normal University (Natural Sciences Edition), 1994, 18(1): 25-28 |
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| Authors: | Shi Xiaobo Li Chungen Lin Bingfa Wu Shenghua |
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| Abstract: | Two new diperoxyditungstates K2W2O5(O2)2 = 4H2O and (Et4N+)2W2O5(O2)2 ?2H2O were prepared by reaction of white powdery tungstic acid with 5% H2O2. Both the peroxytungstates were charater-ized by chemical analysis. IR spectra. UV absorption spectra. X-ray powdery diffraction and thermogram. and the structure of diperoxyditungstate has also been inferred. |
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| Keywords: | diperoxyditungstates preparation structure properties |
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