| 赤霉素环氧衍生物的合成研究 |
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| 引用本文： | 张小华.赤霉素环氧衍生物的合成研究[J].北京工商大学学报(自然科学版),1996(1). |
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| 作者姓名： | 张小华 |
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| 作者单位： | 北京轻工业学院化学工程系 |
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| 摘 要： | 以赤霉素ＧＡ＿３为起始物，经十步，合成了赤霉素的环氧衍生物ｅｎｔ－１３－乙酰氧基－１α，１０α－环氧基－３β－羟基－１－甲基－２０－去甲赤霉素－１６－烯－７，１９－二酸－７，１９－二甲酯，这是一个新化合物．与此同时，还合成了其他三个新化合物，并通过~１Ｈ－ＮＭＲ、~（１３）Ｃ－ＮＭＲ、ＭＳ等分析方法证实了它们的结构．
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| 关 键 词： | 赤霉素，环氧衍生物，半合成 |
THE APPROACH TO THE SYNTHESIS OF THE EPOXIDES OF GIBBERELLINS |
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| Zhang Xiaohua.THE APPROACH TO THE SYNTHESIS OF THE EPOXIDES OF GIBBERELLINS[J].Journal of Beijing Technology and Business University:Natural Science Edition,1996(1). |
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| Authors: | Zhang Xiaohua |
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| Abstract: | The epoxides of gibberellin (ent-13-acetoxy-1α, 10α-epoxy-3β-hydroxy-1-methyl-20-norgibberell-16-en-7, 19-dioic acid, 7, 19-dimethyl ester) which is a new compound was synthesied from gibberellin A_3 by ten steps. At the same time, the other three new compounds were also prepared. The structures were assigned by a combination of ￣1H, ￣(13)C-n. m. r. and mass spectroscopy. |
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| Keywords: | gibberellins epoxides partial synthesis |
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