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电化学体系中非连续型振荡的诱发
引用本文:雷惊雷,罗久里.电化学体系中非连续型振荡的诱发[J].四川大学学报(自然科学版),1999,36(5):918-924.
作者姓名:雷惊雷  罗久里
作者单位:四川大学化学系,四川成都,610064
摘    要:根据非连续型振动与慢流型,双稳态现象之间的内在联系,讨论了演化机制可出现多定态分支的电极反应体系,因外控状态参量慢变化导致非连续型电化学振荡的可能性。模型研究表明,适当的外电路阻抗或反应体系温度控制的热补偿机制的存在,可能诱发该类振荡,从而为抑制或诱发利用该类振荡提供了一条可能的途径。

关 键 词:非连续型电化学振荡  折叠的慢流型  外电路阻抗  热补偿型温度控制

THE INDUCEMENT OF RELAXATION ELECTROCHEMICAL OSCILLATION
LEI Jing-lei,LUO Jiu-li.THE INDUCEMENT OF RELAXATION ELECTROCHEMICAL OSCILLATION[J].Journal of Sichuan University (Natural Science Edition),1999,36(5):918-924.
Authors:LEI Jing-lei  LUO Jiu-li
Abstract:According to the relationship among the folded show mainfold,bistability and relaxation oscillation,to a electrochemical system in which bistability could be found,it is discussed that the possibility of appearance of the relaxation oscillation induced by a externally controlled parameter changes slow.It is turned out that the relaxation electrochemical oscillation could be induced along two approaches:proper arrangement of external electric circuit or suitable temperature controlling of heat compensation type,which is useful to the inducement or inhibition of electrochemical oscillation in experiment.
Keywords:relaxation  electrochemical  oscillation  folded  slow  mainfold  external  electric  circuit  temperature  controlling  of  heat  compensation
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