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热海水中热浸镀用锌及锌铝合金的电化学性能
引用本文:李鑫,杜鸿雁,魏绪钧,李焰. 热海水中热浸镀用锌及锌铝合金的电化学性能[J]. 东北大学学报(自然科学版), 2005, 26(11): 82-85. DOI: -
作者姓名:李鑫  杜鸿雁  魏绪钧  李焰
作者单位:东北大学,材料与冶金学院,辽宁,沈阳,110004;重庆大学,化学化工学院,重庆,400044;中国科学院海洋研究所,山东,青岛,266071
基金项目:中国科学院资助项目,山东省青岛市自然科学基金
摘    要:为了定量比较不同热浸镀层用金属(或合金)在热海水中对钢铁基体的阴极保护作用,参照国标GB/T 17848-1999的要求对几种典型的热浸镀用锌及锌铝合金测试了50℃条件下的恒电流性能,计算了电流效率,观察了腐蚀产物脱落情况及腐蚀均匀性,并据此评价了它们的电化学保护性能.结果表明:Zn的电化学性能最好,Zn-55Al-1.6Si合金的电化学性能最差,Zn-5Al-0.1RE,Zn-5Al-0.5Mg,Zn-6Al-3Mg,Zn-11Al-0.2Si-3Mg,Zn-25Al-0.2Si-0.2Mg和Zn-25Al-0.2Si-0.2RE合金介于二者之间.

关 键 词:热浸镀  热浸镀层  阴极保护  牺牲阳极  电流效率  电化学性能
文章编号:1005-3026(2005)11-1099-04
收稿时间:2005-01-07
修稿时间:2005-01-07

Electrochemical Properties of Zn/Zn-Al Alloys as Hot-Dip Galvanized Coating Protecting Steel in Hot Seawater
LI Xin,DU Hong-yan,WEI Xu-jun,LI Yan. Electrochemical Properties of Zn/Zn-Al Alloys as Hot-Dip Galvanized Coating Protecting Steel in Hot Seawater[J]. Journal of Northeastern University(Natural Science), 2005, 26(11): 82-85. DOI: -
Authors:LI Xin  DU Hong-yan  WEI Xu-jun  LI Yan
Affiliation:(1) School of Materials and Metallurgy, Northeastern University, Shenyang 110004, China; (2) College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, China; (3) Institute of Oceanology, Chinese Academy of Science, Qingdao 266071, China
Abstract:To compare quantitatively the cathodic protection effects of Zn and several Zn-Al alloys as hot-dip galvanized coating materials on steel in 50°C seawater, their electrochemical properties were tested with constant current, according to the China national standard GB/T 17848-1999. Their current efficiencies were then calculated with surface's corrosive peeling and homogeneity observed. Thus, their effects of anti-corrosion protection were evaluated. The results showed that the electrochemical properties of such zinc-aluminum alloys as Zn-5Al-0.1RE, Zn-5Al-0.5Mg, Zn-6Al-3Mg, Zn-11Al-0.2Si-3Mg, Zn-25Al-0.2Si-0.2Mg and Zn-25Al-0.2Si-0.2RE are medium, while Zn is the best and Zn-55Al-1.6Si alloy the poorest one.
Keywords:hot-dip galvanization  coating  cathodic protection  sacrificial anode  current efficiency  electrochemical property
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