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2-(三甲氧基苯基)吲哚的Mannich反应
引用本文:邱玉珠,张正,杭超,胡宏纹.2-(三甲氧基苯基)吲哚的Mannich反应[J].南京大学学报(自然科学版),1991(2).
作者姓名:邱玉珠  张正  杭超  胡宏纹
作者单位:南京大学化学系,南京大学化学系,南京大学化学系,南京大学化学系
摘    要:2-(2,3,4,-三甲氧基苯基)吲哚(1)及2-(3,4,5-三甲氧基苯基)吲哚(2)与甲醛及仲胺反应生成了相应的Mannich碱(1a-1e,2a-2e).吲哚(1,2)与伯胺反应生成了相应的双吲哚Mannich碱(1f-1g,2f-2g).这此吲哚Mannich碱的质谱有许多共性.

关 键 词:吲哚  Mannich碱  质谱

MANNICH REACTION OF 2-(TRIMETHOXYPHENYL) INDOLES
Qiu Yuzhu Zhang Zheng Hang Chao Hu Hongwen.MANNICH REACTION OF 2-(TRIMETHOXYPHENYL) INDOLES[J].Journal of Nanjing University: Nat Sci Ed,1991(2).
Authors:Qiu Yuzhu Zhang Zheng Hang Chao Hu Hongwen
Institution:Department of Chemistry
Abstract:2-(2,3,4-trimethoxyphenyl) indole (1) and 2-(3,4,5-trihiethoxyphenyl) indole (2) reacted with formaldehyde and secondary amines to give the corresponding Mannich bases (la-le, and 2a-2e), respectively, When the above indoles (1 and 2) reacted with primary amines, bis-indole Mannich bases (1f-1g, 2f-2g) were obtained. The mass spectrum of these Mannich bases was discussed.
Keywords:indole  Mannich base  mass spectrum
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