| 对称二环己基取代六元瓜环与对咪唑苯胺自组装实体的晶体结构 |
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| 引用本文： | 吕利宾,张云黔,薛赛凤,祝黔江,陶朱. 对称二环己基取代六元瓜环与对咪唑苯胺自组装实体的晶体结构[J]. 贵州大学学报(自然科学版), 2011, 28(4): 18-21,24 |
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| 作者姓名： | 吕利宾 张云黔 薛赛凤 祝黔江 陶朱 |
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| 作者单位： | 1. 贵州省大环化学及超分子化学重点实验室,贵州贵阳,550025
2. 贵州大学应用化学研究所,贵州贵阳,550025 |
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| 基金项目： | 贵州省科学技术基金资助项目(20102239); 贵州大学引进人才基金资助项目(2010018) |
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| 摘 要： | 本文以(CyH)2Q[6]为主体分子和4-(1H-咪唑-2-基)苯胺盐酸盐为客体分子,通过X-射线单晶衍射方法研究发现,主体与客体分子之间通过离子—偶极作用,客体分子的苯胺部分包结在(CyH)2Q[6]的疏水性空腔内,形成(CyH)2Q[6]部分包结客体分子的1:1主客体包结配合物.又通过离子-偶极作用和氢键互相作用,...
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| 关 键 词： | 关键词:对称二环己基取代六元瓜环 4-(1H-咪唑-2-基)苯胺 X-射线单晶衍射方法 超分子链 晶体结构 |
Crystal Structure of a Novel Self-assembled Complexe of the 1,4-Dicyclohexyl Cucurbit[6]uril with 4-(1H-imidazol-2-yl) aniline |
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| LV Li-bin,ZHANG Yun-qian,XUE Sai-feng,ZHU Qian-jiang,TAO Zhu. Crystal Structure of a Novel Self-assembled Complexe of the 1,4-Dicyclohexyl Cucurbit[6]uril with 4-(1H-imidazol-2-yl) aniline[J]. Journal of Guizhou University(Natural Science), 2011, 28(4): 18-21,24 |
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| Authors: | LV Li-bin ZHANG Yun-qian XUE Sai-feng ZHU Qian-jiang TAO Zhu |
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| Affiliation: | LV Li-bin1,ZHANG Yun-qian1,XUE Sai-feng2,ZHU Qian-jiang2,TAO Zhu2 (1.Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province,Guizhou University,Guiyang 550025,China,2.Institute of Applied Chemistry,China) |
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| Abstract: | In this work,new cage compound-1,4-dicyclohexyl cucurbit[6]uril((CyH)2Q[6]) is selected as host,4-(1H-imidazol-2-yl)aniline(ImBA) are selected as guests,and the interaction of the(CyH)2Q[6] and ImBA have been studied in detail by using single crystal X-ray diffraction determination methods.The results indicat that the phenyl group of ImBA were included in the cavities of(CyH)2Q[6] and a 1:1 complex was formed for(CyH)2Q[6]-ImBA.The crystal structure of the compound shows that a stable pseudorotaxane inclusi... |
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| Keywords: | 1 4-dicyclohexyl cucurbit[6]uril 4-(1H-imidazol-2-yl)aniline X-ray diffraction supramolecular chains crystal structure |
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