| 重谈[Ti(H_2O)_6]~(3 )和[Cu(H_2O)_6]~(2 )的Jahn-Teller效应 |
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| 引用本文： | 王君,高敬群,徐锐,杨威.重谈[Ti(H_2O)_6]~(3 )和[Cu(H_2O)_6]~(2 )的Jahn-Teller效应[J].辽宁大学学报(自然科学版),2000(1). |
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| 作者姓名： | 王君 高敬群 徐锐 杨威 |
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| 作者单位： | 辽宁大学化学系!辽宁沈阳110036(王君，高敬群，徐锐)，辽宁锦化化工(集团)责任有限公司!锦州121006(杨威) |
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| 摘 要： | 采用角重叠理论的方法,计算了三棱柱和八面体以及介于两者之间配体场的d轨道分裂后的能级,由此解释了造成JahnTeller效应的原因是键角的变化,而非键长的变化
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| 关 键 词： | Jahn-Teller效应 角重叠理论 电子光谱 |
Reinvestigation on the Jahn Teller Effect of Complexes [Ti(H_2O)_6]~(3 ) and [Cu(H_2O)_6]~(2 ) |
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| WANG Jun,GAO Jingqun,XU Rui.Reinvestigation on the Jahn Teller Effect of Complexes [Ti(H_2O)_6]~(3 ) and [Cu(H_2O)_6]~(2 )[J].Journal of Liaoning University(Natural Sciences Edition),2000(1). |
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| Authors: | WANG Jun GAO Jingqun XU Rui |
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| Institution: | WANG Jun,GAO Jingqun,XU RuiDepartment of Chemistry,Liaoning University,Shenyang 110036YANG Wei Liability Limited Company,Liaoning Jinhuahuagong Group,Jinzhou 121006 |
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| Abstract: | The d orbital energy levels in triprismatic and octahedral coordinate structures and the intermediate states between triprismatic and octahedral coordinate structures have been calculated by using Angular Overlap Model (AOM). The results explain that it is possible that the variations of the bond angle, not bond length, accounts for Jahn Teller Effect. |
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| Keywords: | Jahn Teller Effect Angular Overlap Model Electronic Spectrum |
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