| 漆酚钛螯合高聚物热分解反应动力学的研究 |
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| 引用本文： | 陈日耀,胡炳环.漆酚钛螯合高聚物热分解反应动力学的研究[J].福建师范大学学报(自然科学版),1994,10(1):77-81. |
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| 作者姓名： | 陈日耀 胡炳环 |
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| 摘 要： | 用非等温热重法研究了漆酚钛螯合高聚物的热分解反应动力学，结果表明漆酚钛螯合高聚物热分解过程是一级反应。用Ｏｚａｗａ（Ｉ）法和Ｒｅｉｃｈ法求得的热分解反应平均活化能分别为３９．１１ｋｃａｌ／ｍｏｌ和３９．８９ｋｃａｌ／ｍｏｌ。
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| 关 键 词： | 漆酚钛 螯合高聚物 热分解 漆料 |
Study on the Thermal Decomposition Kinetics of Urushioltitanium Chelate Polymers Using Thermogravimetry |
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| Chen Riyao,Hu Binghuan,Lin Jinhuo,Chen Wending.Study on the Thermal Decomposition Kinetics of Urushioltitanium Chelate Polymers Using Thermogravimetry[J].Journal of Fujian Teachers University(Natural Science),1994,10(1):77-81. |
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| Authors: | Chen Riyao Hu Binghuan Lin Jinhuo Chen Wending |
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| Institution: | Chen Riyao;Hu Binghuan;Lin Jinhuo;Chen Wending(Experiment Center)(Institute of Polymer Science) |
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| Abstract: | The thermal decomposition kinetics of urushiol-Ti chelate polymers has been stud ied by non-isothermal thermogravimetry.The results suggest that the thermal decomposition kinet ics of urushiol-Ti chelate polymers is first order.The average activation energy of the thermal de composition calculated by Ozawa-(I)method and Reich method are 39.11 kcal/mol and 39.89 kcal/mol respectively. |
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| Keywords: | urushiol-titanium chelate polymers non-isothermal thermogravimetry reaction order activation energy |
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