| 取代苯基锂在乙酰丙酮铁作用下的氧化偶合反应 |
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| 引用本文： | 谢颂凯. 取代苯基锂在乙酰丙酮铁作用下的氧化偶合反应[J]. 中山大学学报(自然科学版), 1987, 0(1) |
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| 作者姓名： | 谢颂凯 |
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| 作者单位： | 中山大学化学系 |
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| 摘 要： | 乙酰丙酮铁,能使邻位锂取代的1,1′-联苯-2,2′-二(甲酸叔丁酯)、N,N-二甲基苯胺及其类似物发生氧化偶合反应.反应条件温和,是一种新的芳环-芳环偶合方法.
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| 关 键 词： | 氧化偶合反应 取代苯基锂 乙酰丙酮铁 芳环-芳环偶合 有机合成新方法 |
The Oxidative Coupling of Ortho-Substituted Phenyllithium with Ferric Acetylacetonate |
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| Xie Songkai. The Oxidative Coupling of Ortho-Substituted Phenyllithium with Ferric Acetylacetonate[J]. Acta Scientiarum Naturalium Universitatis Sunyatseni, 1987, 0(1) |
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| Authors: | Xie Songkai |
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| Affiliation: | Department of Chemistry |
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| Abstract: | The oxidative coupling of some ortho-substituted phenyllithium with ferric acetylacetonate was reported. This novel method of aryl-aryl coupling has advantages of readily available reagent, mild reaction conditions, and good yield of coupling products. Thus, di-tert-butyl 1,1'-biphenyl-2,2'-dicarboxylate,N,N-dimethyl benzylamine aind 2,2'-bis(N,N-dimethylaminomethyl)-1,1'-biphenyl had been dimerized by the method with satisfactory yield. The experimental details were described in this article. |
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| Keywords: | Oxidative coupling substituted phenyllithium ferric ac(?)tylacetonate aryl-aryl coupling new organic synthetic method |
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