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铁-芳烃配合物引发环氧化合物阳离子光聚合反应机理
引用本文:陈旭东,陈用烈.铁-芳烃配合物引发环氧化合物阳离子光聚合反应机理[J].中山大学学报(自然科学版),2000,39(3):122-124.
作者姓名:陈旭东  陈用烈
作者单位:中山大学高分子研究所!广东广州510275
摘    要:研究了铁-芳烃配合物引发环氧化合物阳离子光聚合反机理,讨论了反庆条件对聚合反应的影响。结果表明,聚合反应为n+1级反应,n为环氧化物与引发剂形成的配合物的配位数。

关 键 词:铁-芳烃配合物  环氧化合物  引发剂  阳离子光聚合

Mechanism of Photoinitiated Polymerization of Epoxides Initiated with Iron-arene Complexes
CHEN Xu dong,CHEN Yong lieInstituteofPolymerSciences,ZhongshanUniversity,Guangzhou ,China.Mechanism of Photoinitiated Polymerization of Epoxides Initiated with Iron-arene Complexes[J].Acta Scientiarum Naturalium Universitatis Sunyatseni,2000,39(3):122-124.
Authors:CHEN Xu dong  CHEN Yong lieInstituteofPolymerSciences  ZhongshanUniversity  Guangzhou  China
Institution:CHEN Xu dong,CHEN Yong lieInstituteofPolymerSciences,ZhongshanUniversity,Guangzhou 510 2 75,China
Abstract:The mechanism of photoinitiated polymerization of epoxides initiated with iron arene complexes was studied. The effects of polymerization conditions on photopolymerization were discussed. The results show that the coordination compounds formed by epoxieds and iron arene complexes.
Keywords:iron  arene complex  epoxied  photopolymerization  reaction mechanism
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