| 水溶液中碱金属卤化物-非电解质的焓对作用系数 |
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| 引用本文： | 郝力生,南延青,林瑞森.水溶液中碱金属卤化物-非电解质的焓对作用系数[J].湖南师范大学自然科学学报,2000,23(4):55-58. |
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| 作者姓名： | 郝力生 南延青 林瑞森 |
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| 作者单位： | 1. 湖南师范大学化学化工学院化学系,中国,长沙,410081
2. 浙江大学化学系,中国,杭州,310027 |
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| 基金项目： | 中国科学院资助项目，2860136， |
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| 摘 要： | 根据实验结果获得了２９８．１５Ｋ碱金属氯化物－乙醇在水中的焓对作用系数，并引述了部分文献值，对它们进行了分析和讨论。将基团加和性的概念应用于ＮａＣｌ，ＮａＩ－非电解质的相互作用，得到官能团相互作用参数ｈＮｉ。
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| 关 键 词： | 碱金属卤化物 焓对作用系数 混合溶剂 非电解质 |
| 修稿时间： | 2000-01-27 |
Enthalpic Pair-interaction Coefficients between Alkali Metals Halide and Nonelectrolytes in Water at 298.15 K |
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| HAO Li-sheng,NAN Yan-qing,LIN Rui-sen.Enthalpic Pair-interaction Coefficients between Alkali Metals Halide and Nonelectrolytes in Water at 298.15 K[J].Journal of Natural Science of Hunan Normal University,2000,23(4):55-58. |
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| Authors: | HAO Li-sheng NAN Yan-qing LIN Rui-sen |
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| Abstract: | Enthalpic pair interaction coefficients of alkalic metals chloride enthanol in water at 298 15?K were determined according to the experimental results. In addition to our own experimental results, we incorporated some data reported by literature. Analyses and discussions were carried out. A functional group additivity concept was applied to the interactions between NaCl, NaI and nonelectrolytes. Functional group interaction parameters h Ni were obtained. |
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| Keywords: | alkali metals halid enthalpic pair interaction coefficient mixed solvent |
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