| Hg3S2Cl2的合成和晶体结构 |
| |
| 引用本文： | 陈文通,匡汉茂,陈华龙.Hg3S2Cl2的合成和晶体结构[J].井冈山大学学报（自然科学版）,2011(4):44-47. |
| |
| 作者姓名： | 陈文通 匡汉茂 陈华龙 |
| |
| 作者单位： | 井冈山大学化学化工学院;井冈山大学应用化学研究所;井冈山大学江西省配位化学重点实验室; |
| |
| 基金项目： | The NSF of Jiangxi(2008GQH0001,200007GQH1685) |
| |
| 摘 要： | 通过固相反应合成了一种新相的金属硫属化合物Hg3S2Cl2(1),并对该化合物进行了X-射线单晶结构表征。该化合物属于单斜晶系的C2/m空间群,晶胞参数如下:a=16.741(2),b=9.042(1),c=9.366(1),β=90.346(2)°,V=1417.6(3)3,Z=8,Cl2Hg3S2,Mr=736.79,Dc=6.904g/cm3,S=1.002,μ(MoKα)=66.036mm-1,F(000)=2448,R=0.0368,wR=0.0461。该化合物具有3维框架结构。
|
| 关 键 词： | 氯化物 晶体 框架 汞 硫 |
SYNTHESIS AND CRYSTAL STRUCTURE OF Hg_3S_2Cl_2 |
| |
| CHEN Wen-tong,KUANG Han-mao,CHEN Hua-long.SYNTHESIS AND CRYSTAL STRUCTURE OF Hg_3S_2Cl_2[J].Journal of Jinggangshan University(Natural Sciences Edition),2011(4):44-47. |
| |
| Authors: | CHEN Wen-tong KUANG Han-mao CHEN Hua-long |
| |
| Institution: | CHEN Wen-tong,KUANG Han-mao,CHEN Hua-long(School of Chemistry and Chemical Engineering,Institute of Applied Chemistry,Jiangxi Province Key Laboratory of Coordination Chemistry,Jinggangshan University,Ji'an,Jiangxi 343009,China) |
| |
| Abstract: | A new phase of metal chalcogenide,Hg3S2Cl2（1）,has been prepared via a solid-state reaction and structurally characterized by single-crystal X-ray diffraction.Compound 1 crystallizes in the space group C2/m of the monoclinic system with eight formula units in a cell：a = 16.741（2）,b = 9.042（1）,c = 9.366（1）,β = 90.346（2）,V = 1417.6（3）3,Cl2Hg3S2,Mr = 736.79,Dc = 6.904 g/cm3,S = 1.002,μ（MoKα） = 66.036 mm-1,F（000） = 2448,R = 0.0368 and wR = 0.0461.Compound 1 features a 3-D framework structure. |
| |
| Keywords: | chloride crystal structure 3D framework mercury sulfur |
| 本文献已被 CNKI 维普 等数据库收录！ |
| 点击此处可从《井冈山大学学报（自然科学版）》浏览原始摘要信息 |
| 点击此处可从《井冈山大学学报（自然科学版）》下载免费的PDF全文 |
|
