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苯乙烯和甲基丙烯酸丁酯无乳化剂的乳液共聚
引用本文:龚惠仁,伍辉群. 苯乙烯和甲基丙烯酸丁酯无乳化剂的乳液共聚[J]. 杭州师范学院学报(社会科学版), 1992, 0(3)
作者姓名:龚惠仁  伍辉群
作者单位:杭州师范学院化学系(龚惠仁),杭州师范学院化学系(伍辉群)
摘    要:本文研究了在18-冠(醚)-6存在下,苯乙烯和甲基丙烯酸丁酯无乳化剂乳液共聚。发现18-冠(醚)-6能起到相转移催化作用,加速共聚反应。对实验结果提出两相成核的解释。

关 键 词:苯乙烯  甲基丙烯酸丁酯  无乳化剂  乳液共聚

EMULSIFIER-FREE EMULSION COPOLYMERIZATION OF STYRENE AND BUTYLMETHYLACRYLATE
Gong Huiren Wu Haiqun. EMULSIFIER-FREE EMULSION COPOLYMERIZATION OF STYRENE AND BUTYLMETHYLACRYLATE[J]. Journal of Hangzhou Teachers College(Humanities and Social Sciences), 1992, 0(3)
Authors:Gong Huiren Wu Haiqun
Affiliation:Department of Chemistry
Abstract:The emulsifier-free emulsion copolymerization of styrene and Butylme-thylacrylate in the presence of 18-Crown-6 has been studied. We find that 18-Crown-6 can accelerate the copolymerization reaction as a phase transfer eatalyst. From these resulte, a two phase particle nucleation mechanism has been proposed for this copolymerization.
Keywords:Emulsifier-free emulsion copolymerization  styrene  Butylmethylacrylate.
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