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聚乙二醇相转移催化的Reimer—Tiemann反应
引用本文:杨永甲,皮祖兰.聚乙二醇相转移催化的Reimer—Tiemann反应[J].湖南师范大学自然科学学报,1989,12(4):318-323.
作者姓名:杨永甲  皮祖兰
作者单位:湖南师范大学化学系,湖南师范大学化学系 湖南医科大学
摘    要:

关 键 词:苯酚  取乙二醇  相移催化  R-T反应

POLYETHYLENE GLYCOLS USED AS PHASE TRANSFER CATALYST FOR REIMER-TIEMANN REACTION
Yang Yongjia,Pi Zulan.POLYETHYLENE GLYCOLS USED AS PHASE TRANSFER CATALYST FOR REIMER-TIEMANN REACTION[J].Journal of Natural Science of Hunan Normal University,1989,12(4):318-323.
Authors:Yang Yongjia  Pi Zulan
Institution:Yang Yongjia;Pi Zulan Department of Chemistry
Abstract:In this paper,polyethylene Glycol(PEG)was first used as phase transfer ca- talyst for Reimer-Tiemann reaction.The results of the experiments show that PEG is a good liquid-liquid transfer catalyst.Under phase transfer condition with Ethanal as solvent and PEG-600 as phase transfer catalyst,the yield of salieyl- ldehyde+P-hydroxylenzaldehyde is 93.9%(besed on phonol consumed)and 51.8% (besed on Chloroform).And we were found that the synergism of C_2H_5OH and PEG.
Keywords:phenol  Chloroform  phase shifts  polyethylene oxide/Sallicylaldehyde  O-hydroxybenzaldehyde  P-Hydroxybenzaldehyde  dichlorocarben  Reimer-Tiemann reaction  phase transfer catalyst
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