| Fenton法去除垃圾渗滤液TOC的动力学研究 |
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| 引用本文： | 查甫更,张明旭,高良敏,胡友彪,徐国春. Fenton法去除垃圾渗滤液TOC的动力学研究[J]. 安庆师范学院学报(自然科学版), 2015, 0(3): 71-74. DOI: 10.13757/j.cnki.cn34-1150/n.2015.03.020 |
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| 作者姓名： | 查甫更 张明旭 高良敏 胡友彪 徐国春 |
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| 作者单位： | 1. 安徽理工大学 地球与环境学院,安徽 淮南,232001;2. 铜陵首创水务有限公司,安徽 铜陵,244000 |
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| 摘 要： | 采用修正后一级反应动力学模型拟合Fenton法处理垃圾渗滤液结果,研究初始pH值、试剂比、H2 O2用量、初始浓度和温度等因素对动力学常数的影响并优化反应参数.结果表明：在考虑运行成本情况下,Fenton法处理渗滤液的最佳去除率为70.3%,此时反应条件初始pH值为3,[H2O2]/[TOC0]为4,[H2O2]/[Fe2+]为5,反应温度为室温.
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| 关 键 词： | Fenton法 垃圾渗滤液 TOC 反应动力学模型 |
Kinetics of TOC in Landfill Leachate by Fenton Process |
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| Abstract: | The reaction rate constants, stimulated by the modified first-order kinetic model on treatment of landfill leachate by Fenton process, of different influencing factors such as initial pH, initial hydrogen peroxide concentration, [ H2 O2 ]/[ Fe2+] molar ratio, temperature and initial concentration were discussed. The optimization of Fenton, while the best TOC removal was 70. 3%, was at initial pH at 3, [H2O2]/[TOC0] at 4, [H2O2]/[Fe2+] at 5 and room temperature by simultaneous consideration of economic, kinetic constant and TOC removal efficiency of leachate. |
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| Keywords: | fenton process landfill leachate TOC kinetic model |
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