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正十四烷在柴油机条件下芳香烃的形成及演化
引用本文:鞠洪玲,成晓北. 正十四烷在柴油机条件下芳香烃的形成及演化[J]. 华中科技大学学报(自然科学版), 2011, 39(9): 112-116
作者姓名:鞠洪玲  成晓北
作者单位:华中科技大学能源与动力工程学院,湖北武汉,430074
基金项目:国家自然科学基金资助项目(50976039); 清华大学汽车安全与节能国家重点实验室开放基金资助项目(KF10112)
摘    要:以单缸直喷柴油机为研究背景,考虑了正十四烷(C14H30)燃料的详细化学反应机理,设计了化学成分的焓值计算程序,对缸内燃烧过程进行三维数值模拟计算,研究了诱发碳烟颗粒先导物生成的单环及多环芳香烃(PAHs)的形成,应用Belardini碳烟模型讨论了缸内碳烟颗粒的形成和演变过程,分析了PAHs对碳烟生成的影响.结果表明...

关 键 词:柴油机  碳烟  多环芳香烃(PAHs)  化学反应机理  正十四烷

Polycyclic aromatic hydrocarbon formation during n-tetradecane combustion in diesel engines
Ju Hongling Cheng Xiaobei. Polycyclic aromatic hydrocarbon formation during n-tetradecane combustion in diesel engines[J]. JOURNAL OF HUAZHONG UNIVERSITY OF SCIENCE AND TECHNOLOGY.NATURE SCIENCE, 2011, 39(9): 112-116
Authors:Ju Hongling Cheng Xiaobei
Affiliation:Ju Hongling Cheng Xiaobei(College of Energy and Power Engineering,Huazhong University of Science and Technology,Wuhan 430074,China)
Abstract:Three-dimensional numerical simulation in cylinder combustion was carried out based on a single cylinder direct inject diesel engine,while the detail chemical reaction mechanism of n-tetradecane was considered,and the enthalpy calculate subroutine of chemical species was built.The formation and evolution mechanisms of aromatic(benzene) and polycyclic aromatic hydrocarbon,which were the precursor of soot particle,were calculated.Soot particle mass in cylinder combustion was calculated by Belardini soot model...
Keywords:diesel engine  soot  polycyclic aromatic hydrocarbon(PAHs)  chemical kinetics mechanism  n-tetradecane  
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