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糠醛/8-羟基喹啉铝聚合物复合纳米TiO2光催化剂的研究
引用本文:苟于强,苏致兴.糠醛/8-羟基喹啉铝聚合物复合纳米TiO2光催化剂的研究[J].兰州大学学报(自然科学版),2004,40(5):61-64.
作者姓名:苟于强  苏致兴
作者单位:1. 兰州大学,化学化工学院,甘肃,兰州,730000;兰州医学高等专科学校,甘肃,兰州,730020
2. 兰州大学,化学化工学院,甘肃,兰州,730000
摘    要:通过糠醛/8-羟基喹啉铝聚合物(PFQ)与纳米TiO2的复合制得了光活性很高的催化剂,并通过FTIR,UV-Vis,ESR等手段对光催化剂进行了表征.结果表明糠醛/8-羟基喹啉铝聚合物与纳米TiO2复合后,拓宽了纯纳米TiO2的光谱响应范围,使光催化剂在可见光范同都有很强的吸收.并用该催化剂对甲基橙进行了光降解反应,实验表明在自然光下,该催化剂十几分钟就能使甲基橙染料完全褪色.

关 键 词:糠醛/8-羟基喹啉铝  纳米TiO2  光催化剂  甲基橙
文章编号:0455-2059(2004)05-0061-04

Study of photocatalyst coated nanometer TiO2 with furfural and oxine-Al3+ polymer
GOU Yu-qiang.Study of photocatalyst coated nanometer TiO2 with furfural and oxine-Al3+ polymer[J].Journal of Lanzhou University(Natural Science),2004,40(5):61-64.
Authors:GOU Yu-qiang
Institution:GOU Yu-qiang~
Abstract:Photocatalyst coated nanomeyer TiO_2 with furfural and oxineoAl~(3+) polymer was synthesized using an acid-catalyzed method and characterized by IR, UV-vis and ESR techniques. The results show that the catalysis activity of the photocatalyst of furfural and oxine-Al~(3+) polymer/nanometer TiO_2 complex after calcinations was higher than pure TiO_2 and polymer. The aimed catalyst has been found to be modifying the nanometer TiO_2 with furfural and oxine-Al~(3+) polymer, resulting in the shift of the absorption band to longer wavelength regions, i. e. into the visible light region, whereas pure TiO_2 absorb ultraviolet rays(<380 nm) only. Furthermore studies showed that the photocatalyst employed in this paper could depigmentize methyl orange solution in a few minutes under visible light. Furfural and oxine-Al~(3+) polymer/TiO_2 complex after calcinations was a photocatalyst with high catalytical activity.
Keywords:furfural/oxine-aluminum  nanometer TiO_2  photocatalyst  methyl orange
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