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Effects of PSMA and experimental conditions on the morphologies of BaCO_3 whiskers
作者姓名:CHENG Bei  YU Xiaoxiao  YU Jiaguo  ZHAO XiujianState Key Laboratory of Advanced Technology for Material Synthesis and Processing  Wuhan University of Technology  Wuhan  China
作者单位:CHENG Bei,YU Xiaoxiao,YU Jiaguo,ZHAO XiujianState Key Laboratory of Advanced Technology for Material Synthesis and Processing,Wuhan University of Technology,Wuhan 430070,China
摘    要:Effects of PSMA and experimental conditions on the morphologies of BaCO_3 whiskers


Effects of PSMA and experimental conditions on the morphologies of BaCO_3 whiskers
CHENG Bei,YU Xiaoxiao,YU Jiaguo,ZHAO XiujianState Key Laboratory of Advanced Technology for Material Synthesis and Processing,Wuhan University of Technology,Wuhan ,China.Effects of PSMA and experimental conditions on the morphologies of BaCO_3 whiskers[J].Journal of University of Science and Technology Beijing,2006(8).
Authors:CHENG Bei  YU Xiaoxiao  YU Jiaguo  ZHAO XiujianState Key Laboratory of Advanced Technology for Material Synthesis and Processing  Wuhan University of Technology  Wuhan  China
Institution:CHENG Bei,YU Xiaoxiao,YU Jiaguo,ZHAO XiujianState Key Laboratory of Advanced Technology for Material Synthesis and Processing,Wuhan University of Technology,Wuhan 430070,China
Abstract:BaCO_3 whiskers exhibiting different morphologies were fabricated by a simple precipitation reaction of barium chloride with sodium carbonate in the absence and presence of poly-(styrene-alt-maleic acid) (PSMA) as a crystal growth modifier at room temperature. The as-prepared products were characterized by scanning electron microscopy (SEM),transmission electron microscopy (TEM),and X-ray diffraction (XRD). The influences of experimental parameters on the size and morphology of BaCO_3 whiskers were investigated and discussed. It was found that the as-prepared BaCO_3 whiskers are single crystals with diameter ranging from 100 to 300?nm,and grow along the crystallographic a-axis or 100] direction. BaCO_3 whiskers with different morphologies,such as branching and dendritic structure,can be obtained depending on the experimental conditions. With increasing PSMA concentration,the diameter of BaCO_3 whiskers decreases.
Keywords:BaCO_3 whiskers  morphological control  poly-(styrene-alt-maleic acid)  single crystal
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