| 联苯双重氮氟硼酸盐二苯-1δ-冠-6络合物的XPS实验与电子结构研究 |
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| 引用本文： | 曹大平,田安民,鄢国森,蒋志成. 联苯双重氮氟硼酸盐二苯-1δ-冠-6络合物的XPS实验与电子结构研究[J]. 四川大学学报(自然科学版), 1988, 0(4) |
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| 作者姓名： | 曹大平 田安民 鄢国森 蒋志成 |
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| 作者单位： | 兰州大学化学物理所 |
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| 摘 要： | 用XPS实验和EHMO近似计算方法对新型冠醚络合物——联苯双重氮二苯—18—冠—6(l:2)络合物的结构与电子结构进行了研究。在计算中采用了重氮离子插入冠醚环内,并对各种构型和插入位置进行了优化,计算结果与实验事实相符,证明了这种结构的合理性。
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| 关 键 词： | 联苯双重氮氟硼酸盐二苯—18—冠—6络合物 光电子能谱 络合物电子结构 |
THE XPS AND ELECTRONIC STRUCTURE FOR DIBENZO-18-CROWN-6 COMPLEX OF BIPHENYL BIDIAZONIUM TETRAFLUOROBORATE |
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| Cao Doping Tian Anmin Yan Guosen Jiang Zhicheng. THE XPS AND ELECTRONIC STRUCTURE FOR DIBENZO-18-CROWN-6 COMPLEX OF BIPHENYL BIDIAZONIUM TETRAFLUOROBORATE[J]. Journal of Sichuan University (Natural Science Edition), 1988, 0(4) |
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| Authors: | Cao Doping Tian Anmin Yan Guosen Jiang Zhicheng |
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| Affiliation: | Cao Doping Tian Anmin Yan Guosen Jiang Zhicheng |
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| Abstract: | The electronic Structure of an organic Crown complex, dibenzo-18- Crown-6 2;1 complex of biphenyl bidiazonium tetrafluoroborate, have been studied by XPS and EHMO method. The Structure that diazonium ion inserts its. neck into the crown circle is assumed. The insertion direction of diazonium ion and the configuration of the complex ion are optimized in calculation. The calculation results suggest that the structure is reasonable. |
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| Keywords: | Dibenzo-18-crown-6 complex of biphenyl bidiazonium tetrafluorobotate XPS structure of complex. |
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