| 甲烷转化反应平衡常数的统计理论 |
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| 引用本文： | 王正刚.甲烷转化反应平衡常数的统计理论[J].北京理工大学学报,1988(2). |
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| 作者姓名： | 王正刚 |
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| 作者单位： | 北京工业学院化学工程系 |
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| 摘 要： | 本文根据光谱数据利用统计力学理论方法,并考虑了某些分子的非谐性和非刚性修正,精确计算了甲烷两种转化反应在298K、500K、1000K、1500K温度下的平衡常数,所得结果与宏观热力学方法结果基本一致。
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| 关 键 词： | 甲烷 统计热力学 平衡常数 配分函数 |
STATISTICAL THEORY OF EQUILIBRIUM CONSTANTS FOR TRANSFORMATION REACTIONS OF METHANE |
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| Wang Zhenggang.STATISTICAL THEORY OF EQUILIBRIUM CONSTANTS FOR TRANSFORMATION REACTIONS OF METHANE[J].Journal of Beijing Institute of Technology(Natural Science Edition),1988(2). |
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| Authors: | Wang Zhenggang |
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| Institution: | Department of Chemical Engineering |
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| Abstract: | Equilibrium constants of two fransformation reactions of methane at 298K, 500K, 1000K, 1500K have been exactly calculated on the basis of precise spectrum data by the statistical thermodynamic method, taking into consideration anharmonious and nonrigidity corrections for diatomic molecules rotation and vibration. The results are here given and compared with those obtained through the macroscopic method. |
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| Keywords: | methane statistical thermodynamics equilibrium constant par- tit ion function |
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