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Co-BiVO4的制备及其用于光催化降解含酚废水的研究
引用本文:魏耀旺.Co-BiVO4的制备及其用于光催化降解含酚废水的研究[J].延安大学学报(自然科学版),2011,30(3):64-67,70.
作者姓名:魏耀旺
作者单位:陕西延长石油集团有限公司榆林炼油厂,陕西榆林,718500
摘    要:以Bi(NO3)3.5H2O、NH4VO3和Co(H3CO2)2.4H2O为原料,采用水热法合成光催化剂Co-BiVO4,并对其进行了XRD、UV-visDRS表征。以模拟含酚废水为目标物,以不同的催化剂、光源、催化剂的量及通气量为考察对象,研究了Co-BiVO4催化剂的光催化性能。结果表明,Co-BiVO4在光源为金卤灯(400 W),前驱物pH=7,光照时间60 min左右,催化剂用量1.0 mg/mL,通气量为200 mL/min的条件下,对模拟含酚废水的降解率可达到95%以上。

关 键 词:Co-BiVO4  水热合成  光催化  含酚废水  降解率

Preparation of Co-BiVO4 Photocatalyst and Its Application in the Photocatalytic Oxidative of Phenol-Containing wastuater
WEI Yao-wang.Preparation of Co-BiVO4 Photocatalyst and Its Application in the Photocatalytic Oxidative of Phenol-Containing wastuater[J].Journal of Yan'an University(Natural Science Edition),2011,30(3):64-67,70.
Authors:WEI Yao-wang
Institution:WEI Yao-wang (Shaanxi Yanchang Petrpleum group Co.LTD,Shaanxi Yulin 718500)
Abstract:A visible-light-induced photocatalyst Co-BiVO4 was prepared by hydrothermal method,using Bi(NO3)3·5H2O、NH4VO3 and Co(H3CO2)2·4H2O as reactants.The as-prepared samples were characterized by XRD and UV.The photocatalytical activity was studied by degrading volatile phenol in wastewater.The results show that,the degradation rate of Co-BiVO4 to volatile phenol in wastewater can reach 95% above,under the optimal conditions,which is 1.0mg/mL of catalyst,200mL/min of air,pH=7 of precursors,400w of Metal Halide light.
Keywords:Co-BiVO4  hydrothermal synthesis  photocatalytic  hydroxybenzene wastewater  degradation rate
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