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冰点以下天然气水合物的生成动力学研究
引用本文:王胜杰,韩小辉,郝妙莉,刘芙蓉.冰点以下天然气水合物的生成动力学研究[J].西安交通大学学报,2002,36(1):99-102.
作者姓名:王胜杰  韩小辉  郝妙莉  刘芙蓉
作者单位:西安交通大学环境与化学工程学院,西安,710049
基金项目:陕西省自然科学基金资助项目 (98C19),教育部“教育振兴行动计划”资助项目
摘    要:通过实验研究了冰点以下天然气水合物的生成反应中压力,温度及冰粒大小等因素的影响。并研究了过冷和过压在水合物生成中的作用。实验结果表明:压力越高,温度越低,冰粒越小,越有利于水合物的生成,并且过冷及过压程度和过压时间均促进水合物的生成,得出了衡量反应进行程度的天然气水合物含气率随反应进行时间的关系曲线。

关 键 词:冰点  天然气水合物  生成动力学  反应压力  反应温度  含气率  冰粒大小
文章编号:0253-987X(2002)01-0099-04

Kinetics of Formation of Natural Gas Hydrate below Ice Point
Wang Shengjie,Han Xiaohui,Hao Miaoli,Liu Furong.Kinetics of Formation of Natural Gas Hydrate below Ice Point[J].Journal of Xi'an Jiaotong University,2002,36(1):99-102.
Authors:Wang Shengjie  Han Xiaohui  Hao Miaoli  Liu Furong
Abstract:The influence of pressure, temperature and particle size of ice on the formation of natural gas hydrate below ice point was experimentally investigated, and the influence of supercooling and overpressure was also studied. The results show that the formation would be enhanced by increasing pressure, decreasing temperature and reducing the particle size of ice. It was also obtained that the supercooling or the overpressure degree and time could stimulate the formation of hydrate. The curve of the gas content in natural gas hydrate versus time was also obtained, which can be used to evaluate the reaction degree.
Keywords:natural gas  hydrate  kinetics
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