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泡沫水泥-粉煤灰材料的强度及其电化学特性
引用本文:张凯信,韩鹏举,王效渊,何斌,马富丽.泡沫水泥-粉煤灰材料的强度及其电化学特性[J].科学技术与工程,2020,20(7):2851-2857.
作者姓名:张凯信  韩鹏举  王效渊  何斌  马富丽
作者单位:太原理工大学土木工程学院,太原 030024;太原理工大学土木工程学院,太原 030024;太原理工大学土木工程学院,太原 030024;太原理工大学土木工程学院,太原 030024;太原理工大学土木工程学院,太原 030024
基金项目:山西省人才专项优秀人才科技创新项目(2018年)、国家自然科学基金项目(41807256)、岩土力学与工程国家重点实验室资助课题(Z017003)、同济大学岩土及地下工程教育部重点实验室开放 基金(KLE-TJGE-B1701)、河海大学岩土力学与堤坝工程国家教育部实验室开放基金项目(201702)
摘    要:基于水泥基材料的电化学体系,研究了冻融条件下不同粉煤灰掺量对泡沫轻质水泥基材料的无侧限抗压强度与电化学参数的影响规律,建立相应的等效电路模型,分析表明:随着粉煤灰掺量的增加,造成胶体之间产生“滑移”现象,使得材料抗压强度不断降低;Nyquist图由高频段与中频段两个时间常数及低频区的扩散阻抗组成,相应的等效电路模型中的Q和Cd不断减小,Rt、W、Rl与Rs不断增大;泡沫轻质水泥-粉煤灰材料的强度与电化学元件参数间为指数关系。

关 键 词:粉煤灰  无侧限抗压强度  水泥  轻质  等效电路  电化学阻抗谱
收稿时间:2019/6/13 0:00:00
修稿时间:2019/10/29 0:00:00

Study on strength and electrochemical characteristics of lightweight cement flyash materials (FCF)
Zhang Kaixin,Han Pengju,Wang Xiaoyuan,He Bin,Ma Fuli.Study on strength and electrochemical characteristics of lightweight cement flyash materials (FCF)[J].Science Technology and Engineering,2020,20(7):2851-2857.
Authors:Zhang Kaixin  Han Pengju  Wang Xiaoyuan  He Bin  Ma Fuli
Institution:College of Architecture and Civil Engineering, Taiyuan University,,,,
Abstract:Based on the electrochemical system of cement based materials, the effects of different fly ash content on the unconfined compressive strength and electrochemical parameters of the lightweight cement based materials under freeze-thaw conditions were studied, and the corresponding equivalent circuit models were established. The analysis showed that with the addition of fly ash, the "slippage" phenomenon between the colloids was caused, and the compressive strength of the materials decreased.; Nyquist diagram is composed of two time constants in high frequency band and medium frequency band and diffusion impedance in low frequency band. The corresponding Q and Cd of the equivalent circuit model decrease continuously, and the Rt, W, Rl and Rs increase continuously.
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