| MCM–41介孔分子筛中负载酞菁配合物的研究 |
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| 引用本文： | 崔子祥,薛永强,李萍.MCM–41介孔分子筛中负载酞菁配合物的研究[J].西南石油大学学报（自然科学版）,2012(5):153-158. |
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| 作者姓名： | 崔子祥 薛永强 李萍 |
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| 作者单位： | 太原理工大学化学化工学院;山西大学环境科学与工程研究中心 |
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| 基金项目： | 国家自然科学基金资助(20472014) |
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| 摘 要： | 合成了Zn–酞菁化合物,通过水热法将酞菁化合物负载在MCM–41介孔分子筛中。利用FT–IR、UV–vis–Nir、XRD、FESEM、TEM及N2吸附–脱附仪对酞菁负载后的样品进行了表征。研究结果表明:较高浓度Zn–酞菁能够负载到介孔分子筛中,并且随着酞菁配合物浓度的增加,介孔分子筛孔道的有序性及结晶度都提高。
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| 关 键 词： | MCM–41 负载 Zn–酞菁配合物 |
Study of Metal-phthalocyanine Encapsulated in Mesoporous Molecular Sieves MCM-41 |
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| Cui Zixiang,Xue Yongqiang,Li Ping.Study of Metal-phthalocyanine Encapsulated in Mesoporous Molecular Sieves MCM-41[J].Journal of Southwest Petroleum University(Seience & Technology Edition),2012(5):153-158. |
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| Authors: | Cui Zixiang Xue Yongqiang Li Ping |
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| Institution: | 1.College of Chemistry and Chemical Engineering;Taiyuan University of Technology,Taiyuan,Shanxi 030024,China 2.Search Center of Environmental Science and Engineering,Shanxi University,Taiyuan,Shanxi 030006,China |
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| Abstract: | Zn-phthalocyanine complex(Ⅱ),which periphery has substituents was synthesized,and encapsulated in mesoporous molecular sieves MCM-41.The prepared samples was characterized by FT-IR,UV-vis-Nir,XRD,FESEM,TEM and N2 adsorption-desorption instrument.The research shows that the prepared phthalocyanine copper zinc can be encapsulated in mesoporous molecular sieves MCM-41 in the form of monomer and dipolymer.The prepared phthalocyanine zinc with high concentration encapsulated in MCM-41 is in favour of preparing mesoporous molecular sieves samples with higher crystallinity and pore canal order. |
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| Keywords: | MCM-41 load phthalocyanine |
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