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驱油用抗温空气泡沫体系研究
引用本文:杨怀军,丁亚军,孙琳,旷曦域,王晓超.驱油用抗温空气泡沫体系研究[J].西南石油大学学报(自然科学版),2012,34(5):93-98.
作者姓名:杨怀军  丁亚军  孙琳  旷曦域  王晓超
作者单位:1. 中国石油大港油田分公司采油工艺研究院,天津塘沽3002802. 中国石油大港油田分公司勘探开发研究院,天津塘沽3002803. 西南石油大学石油工程学院,四川成都6105004. 西南石油大学研究生院,四川成都610500
摘    要:空气泡沫驱技术全面的驱油机理与独特的气源优势令其发展应用前景广泛。为保证该技术在高温油藏的成功应用,开展了抗温空气泡沫体系的相关研究。通过在温度110 ℃、地层水矿化度6  104 mg/L 条件下,对10 种耐温表面活性剂起泡体积和析液半衰期的考察,筛选出高温泡沫性能良好的阴非离子表面活性剂LS。模拟油藏条件对LS 的泡沫性能进行了评价,结果表明,LS 在高压密闭条件下能形成比常压下更丰富的泡沫,且多孔介质的持续剪切、空气的持续供给有利于产生丰富的泡沫。向LS 中添加浓度0.1% 以上的稳泡剂WP,可明显提高其析液半衰期;将0.2%LS+0.1%WP 的泡沫体系在110 ℃、6  104 mg/L 下老化90 d,析液半衰期仅缩短20%,与大港官80 油田原油的界面张力保持在10􀀀2 mN/m。同时,空气泡沫体系原油乳化分散性能良好,且能实现油水的彻底分离。

关 键 词:空气泡沫  抗温  起泡体积  半衰期  高压  乳化  

Research on Temperature Resist Air Foam System for Flooding
Yang Huaijun,Ding Yajun,Sun Lin,Kuang Xiyu,Wang Xiaochao.Research on Temperature Resist Air Foam System for Flooding[J].Journal of Southwest Petroleum University(Seience & Technology Edition),2012,34(5):93-98.
Authors:Yang Huaijun  Ding Yajun  Sun Lin  Kuang Xiyu  Wang Xiaochao
Institution:1. Oil Production Technology Institute,Dagang Oilfield Company,CNPC,Tanggu,Tianjin 300280,China2. Research Institute of Petroleum Exploration & Development,Dagang Oilfield Company,CNPC,Tanggu,Tianjin 300280,China3. School of Petroleum Engineering,South West Petroleum University,Chengdu,Sichuan 610500,China4. Graduate School of South West Petroleum University,Chengdu,Sichuan 610500,China
Abstract:Air foam flooding has very bright future because of its comprehensive displacement mechanism and unique air source predominance.To apply the technique successfully in high temperature reservoir,this paper conducted study on the temperature resist air foam system.By examining the foam volume and liquid separating half-life period of ten temperature resist surfactants at 110 ℃ and 6 × 104 mg/L,we screen out the anionic-nonionic surfactant LS which has satisfactory high temperature foam performance.We evaluate the foam performance of LS at reservoir environment and the result shows that LS could form more abundant foam at high pressure seal condition than atmospheric pressure;the persistent shear of porous media and plenty air flow is in favor of LS fully playing its foam performance.By adding foam stabilizer WP whose concentration is beyond0.1%,theliquidseparatinghalf-lifeperiodofLScouldbeevidentlyenhanced.Afteragingunder110 ℃ and6×104mg/L for 90 d,the liquid separating half-life period of 0.2%LS+0.1%WP only shortens by 20%,and its IFT with Guan80 crude oil remains 10 2mN/m.Furthermore,the emulsification capability of air foam is satisfactory,oil and water being separated almost completely after standing short length of time.
Keywords:air foam  temperature resist  foam volume  half-life period  high pressure  emulsification
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