| 联二萘酚衍生氨基吡啶类配体的合成 |
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| 引用本文： | 李建真,阚莎莎,刘全忠. 联二萘酚衍生氨基吡啶类配体的合成[J]. 西华师范大学学报(哲学社会科学版), 2011, 0(1) |
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| 作者姓名： | 李建真 阚莎莎 刘全忠 |
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| 作者单位： | 西华师范大学化学化工学院; |
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| 基金项目： | 国家自然科学基金(20772097)资助项目 |
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| 摘 要： | 本文报道了2,6-二氨基吡啶与(S)-联二萘酚衍生的二溴化合物反应,合成了具有双氮杂环的氨基吡啶类配体.利用该配体与金属化合物络合,催化傅克反应,得到了较高的收率,但没有立体选择性.
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| 关 键 词： | 2 6-二氨基吡啶 光学活性 (S)-联二萘酚 配体 傅克反应 立体选择 |
Synthesis of Aminopyridine Ligands Bearing Optically Activity(S)-BINOL Derivative |
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| LI Jian-zhen,KAN Sha-sha,LIU Quan-zhong. Synthesis of Aminopyridine Ligands Bearing Optically Activity(S)-BINOL Derivative[J]. Journal of China West Normal University:Natural Science Edition, 2011, 0(1) |
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| Authors: | LI Jian-zhen KAN Sha-sha LIU Quan-zhong |
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| Affiliation: | LI Jian-zhen,KAN Sha-sha,LIU Quan-zhong(College of Chemistry and Chemical Engineering,China West Normal University,Nanchong,637000,China) |
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| Abstract: | Nitrogen heterocyclics aminopyridine ligands were synthesized by using bromination of(S)-BINOL derivatives and 2,6-diaminopyridine.The Friedel-Crafts reaction catalyzed by those ligands and metal were carried out,and good productivities were obtained,but without stereoselectivelies. |
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| Keywords: | 2 6-diaminopyridine (S)-BINOL ligands Friedel-Crafts reaction stereoselectivity |
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