| 胶体晶体及三维有序多孔材料的制备 |
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| 引用本文： | 唐天,曾钫,李娜,孙再武,童真. 胶体晶体及三维有序多孔材料的制备[J]. 华南理工大学学报(自然科学版), 2003, 31(10): 73-76 |
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| 作者姓名： | 唐天 曾钫 李娜 孙再武 童真 |
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| 作者单位： | 华南理工大学,材料科学与工程学院,广东,广州,510640 |
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| 基金项目： | 教育部优秀青年教师计划资助项目，广州市科技计划项目 (2 0 0 2J1 C0 0 5 1 )，广东省自然科学基金资助项目 (0 1 5 0 36 )，华南理工大学高水平大学建设资助项目 |
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| 摘 要： | 以粒径为80～320nm的单分散苯乙烯／苯乙烯磺酸钠共聚微球为原料，采用一种全新而简单的制备高度有序胶体晶体模板的方法，利用静电相互作用、表面张力以及蒸发过程中的离子扩散等作用在液面形成了不合溶剂的高度有序的胶体晶体．将溶胶-凝胶前驱液在毛细效应作用下渗入胶体晶体间隙，待前驱液固化后，经煅烧去除苯乙烯微球，制备出了具有三维有序结构的多孔材料——倒置蛋白石．
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| 关 键 词： | 胶体晶体 溶胶-凝胶法 倒置蛋白石 三维有序多孔材料 |
| 文章编号： | 1000-565X(2003)10-0073-04 |
| 修稿时间： | 2003-05-15 |
Preparation of Colloidal Crystals and Three-dimensional Porous Materials |
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| Tang Tian Zeng Fang Li Na Sun Zai wu Tong Zhen. Preparation of Colloidal Crystals and Three-dimensional Porous Materials[J]. Journal of South China University of Technology(Natural Science Edition), 2003, 31(10): 73-76 |
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| Authors: | Tang Tian Zeng Fang Li Na Sun Zai wu Tong Zhen |
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| Abstract: | The monodispersed and highly charged poly(styrene/sodium styrene sulphonate) spheres were prepared with their particle sizes ranging from 80 to 320 nm by emulsifier free emulsion polymerization. A new and simple procedure for producing highly ordered colloidal crystalline template was developed, and the solvent free colloidal crystals were formed on the surface by electrostatic interaction, surface tension as well as the ion diffusion during the evaporation. Then the sol gel solution was infiltrated into the interstitial space of the colloidal crystals through capillary effect and ordered inverse opals were obtained after the solidification of the sol gel solution and the calcification of the polystyrene beads. |
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| Keywords: | colloidal crystal sol gel method inverse opal three dimensional porous material |
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