Synthesis and characterization of sidechain liquid cryastalline polysiloxanes containting either cholesteryl or cyanobiphenyl mesogenic groups |
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Authors: | Xu Guangwei Huang Ronghua Zhang Xianliang |
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Institution: | (1) Department of Chemistry, Wuhan University, 430072 Wuhan, China |
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Abstract: | A series of side-chain liquid crystalline polysiloxanes containing either cholesteryl or cyanobiphenyl mesogenic groups were
synthesized by the hydrosilylation reaction of a polysiloxane containing Si−H group with a vinyl-terminated compound containing
the mesogenic group. Their chemical structures were confirmed by IR,1H NMR, and elemental analysis, Their phase behaviors were investigated by differential scanning calorimetry, optical polarizing
microscope, and X-ray diffraction technique. The results show that all these polysiloxanes except P V display smectic or nematic
mesonorphism or both. The dependence of phase transition temperature on the rigidity of mesogenic unit. the length of spacer
group, and the flexibility of
chain is also described.
Supported by the National Natural Science Foundation of China
Xu Guangwei: born in June 5, 1970, Postgraduate |
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Keywords: | polysiloxane liquid crystal phase behavior mesogenic groups |
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