| 一种高折光指数聚合物透明树脂的合成与性质 |
| |
| 引用本文： | 尹玖梅,陈锡宏,赵登峰,林权. 一种高折光指数聚合物透明树脂的合成与性质[J]. 吉林大学学报(理学版), 2008, 46(3): 539-542 |
| |
| 作者姓名： | 尹玖梅 陈锡宏 赵登峰 林权 |
| |
| 作者单位： | 1. 吉林大学 化学学院超分子结构与材料重点实验室, 长春 130012; 2. 秦皇岛奥莱特腈纶有限公司, 河北 秦皇岛 066000 |
| |
| 摘 要： | 将具有高折光指数的硫和苯环等基团引入含C=C化合物的分子结构中制备了单体甲基丙烯酸苯硫酚酯（PTMA）, 并利用 FTIR,1H NMR和HPLC等技术对其结构进行表征. 将PTMA作为单体与苯乙烯进行共聚, 制备得到含硫透明光学树脂. 对其性能测试结果表明, 共聚树脂具有较高的可见光透光率, 而且随着PTMA质量分数的增加, 树脂的折光指数和密度线性增大, 冲击强度提高.
|
| 关 键 词： | 光学树脂 折光指数 透明性 |
| 文章编号： | 1671-5489(2008)03-0539-04 |
| 收稿时间： | 2007-09-29 |
| 修稿时间： | 2007-09-29 |
Synthesis and Properties of Polymer Transparent Resins with High Refractive Index |
| |
| YIN Jiu-mei,CHEN Xi-hong,ZHAO Deng-feng,LIN Quan. Synthesis and Properties of Polymer Transparent Resins with High Refractive Index[J]. Journal of Jilin University: Sci Ed, 2008, 46(3): 539-542 |
| |
| Authors: | YIN Jiu-mei CHEN Xi-hong ZHAO Deng-feng LIN Quan |
| |
| Affiliation: | 1. Key Lab of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, China;2. Aolaite Qinglun Company, Qinhuangdao 066000, Hebei Province, China |
| |
| Abstract: | Benzene ring and sulphur groups were introduced into a compound containing C=C double bonds to prepare a novel monomer S phenylthio methacrylate (PTMA), the structure of which was characterized by 1H NMR, FTIR and HPLC. The new kinds of transparent polymeric resins were obtained through the copolymerization of PTMA and styrene. The copolymer resins possessed high refractive indexes with a good transparency. With the content of PTMA increasing, the refractive index of the copolymer resin was enhanced, and the impact resistance was improved. |
| |
| Keywords: | optical resin refractive index transparency |
| 本文献已被 维普 万方数据 等数据库收录！ |
| 点击此处可从《吉林大学学报(理学版)》浏览原始摘要信息 |
|
点击此处可从《吉林大学学报(理学版)》下载全文 |
|
