| 多核桥式配合物[dppf(μ-Br)2Nidpe][PF6]合成表征及CV性质 |
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| 引用本文： | 黄兆华,童连凤,黄尊行.多核桥式配合物[dppf(μ-Br)2Nidpe][PF6]合成表征及CV性质[J].福州大学学报(自然科学版),1999,27(2). |
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| 作者姓名： | 黄兆华 童连凤 黄尊行 |
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| 作者单位： | 福州大学化学系!福州，３５０００２ |
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| 基金项目： | 福建省自然科学基金！B96007 |
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| 摘 要： | 配合物［ｄｐｐｆＮｉ（μ-Ｂｒ）２Ｎｉｄｐｅ］［ＰＦ６］（Ⅰ）由ｄｐｅＮｉＢｒ２和ｄｐｐｆＮｉＢｒ２在Ｔ１ＰＦ６的热甲醇溶液中，透光下合成．ＩＲ和ＨＮＭＲ谱表明为溴桥配合物．ＣＶ图表明稳定性较好，并研究了其电化学反应机理．
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| 关 键 词： | 配合物 合成 循环伏安 核磁共振 |
Synthesis Characterization and CV Study Herternuclear Complex |
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| Huang Zhaohu,Tong Lianfeng,Huang Zunxing.Synthesis Characterization and CV Study Herternuclear Complex[J].Journal of Fuzhou University(Natural Science Edition),1999,27(2). |
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| Authors: | Huang Zhaohu Tong Lianfeng Huang Zunxing |
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| Abstract: | The title complex has been synthesized by the reaction between the solution ofDpeNiBr_2 in CHCl_3 and dppfNiBr_2. The reaction must be in the solution of T1PF_6 inCH_3OH, and must avoid light. Its IR and HNMR are studied. We can determine that thereare Br-bridges in the complex. The CV in CH_2Cl_2 shows that it is a stable complex and itsmechannism of electrochemistry is studied. |
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| Keywords: | complex synthesis cyclic voltammeter nuclear magnetic resonance |
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