| 阴极间接电氧化的研究 --媒质钨酸盐/过钨酸盐体系 |
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| 引用本文： | 崔宝秋,张越,赵建玲,张雪英,顾登平. 阴极间接电氧化的研究 --媒质钨酸盐/过钨酸盐体系[J]. 河北师范大学学报(自然科学版), 2000, 24(1): 67-69 |
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| 作者姓名： | 崔宝秋 张越 赵建玲 张雪英 顾登平 |
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| 作者单位： | 河北师范大学化学系,河北石家庄,050016 |
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| 摘 要： | 根据钨酸钠／过钨酸钠氧化还原媒质催化Ｏ２在阴极电还原产生的Ｈ２Ｏ２体系来间接氧化有机物的特点，对阴极间接电氧化体系Ｏ２电还原ＨＯ２Ｏ２的电流效率分别从ＰＨ值、温度、等因素进行最佳工艺条件的选择，从而得出最佳工艺条件，为进一步研究该体系打下基础。
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| 关 键 词： | 阴极间接电氧化 钨酸盐 过钨酸盐 氧化还原 |
| 文章编号： | 1000-5854(2000)01-0067-03 |
Study of Cathodic Indirect Electrooxidation--Tungstate/Pertungstate Redox Midiator System |
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| CUI Boo-qiu,ZHANG Yue,ZHAO Jian-ling,ZHANG Xue-ying,GU Deng-ping. Study of Cathodic Indirect Electrooxidation--Tungstate/Pertungstate Redox Midiator System[J]. Journal of Hebei Normal University, 2000, 24(1): 67-69 |
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| Authors: | CUI Boo-qiu ZHANG Yue ZHAO Jian-ling ZHANG Xue-ying GU Deng-ping |
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| Affiliation: | CUI Boo-qiu,ZHANG Yue,ZHAO Jian-ling,ZHANG Xue-ying,GU Deng-ping(Department of Chemistry .Hebei Normal Uaiversity.Shijiazhuang 050016,China) |
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| Abstract: | We study a tungstate/pertungstate redox midiator combined with cathoically generated hydrogen peroxide from dioxygen. Influences of pH,temperature,current density and charge passed on the current effiencies for the reduction of dioxygen were examined. |
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| Keywords: | cathodic indirect electrooxidation tungstate/pertungstate hydrogen peroxide generated from dioxygen |
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