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HDPE/PA6层状共混阻隔材料的研制
引用本文:邓剑如,盛亚俊.HDPE/PA6层状共混阻隔材料的研制[J].湖南大学学报(自然科学版),2005,32(5):79-82.
作者姓名:邓剑如  盛亚俊
作者单位:湖南大学,化学化工学院,湖南,长沙,410082;湖南大学,化学化工学院,湖南,长沙,410082
基金项目:湖南省杰出中青年专家基金资助项目(VIJZYZ101)
摘    要:通过改变单螺杆吹瓶机的温度分布与螺杆转速,研究了温度分布及螺杆速率对高密度聚乙烯(HDPE)/尼龙6(PA6)共混物分散形态的影响.结果表明:合适的温度控制和较低的螺杆转速有利于分散相PA6层状结构的形成,研制出的层状共混吹塑瓶对烃类溶剂的阻隔性能较HDPE中空吹塑瓶有了较大幅度的提高,对芳烃类溶剂的阻隔性能提高达40倍。而机械强度保持良好.

关 键 词:聚乙烯  尼龙6  层状共混  阻隔性能  吹塑成型
文章编号:1000-2472(2005)05-0079-04
收稿时间:11 11 2004 12:00AM
修稿时间:2004-11-11

Preparation and Barrier Properties of HDPE/PA6 Blend With Laminar Structure
DENG Jian-ru,SHENG Ya-jun.Preparation and Barrier Properties of HDPE/PA6 Blend With Laminar Structure[J].Journal of Hunan University(Naturnal Science),2005,32(5):79-82.
Authors:DENG Jian-ru  SHENG Ya-jun
Institution:College of Chemistry and Chemical Engineering, Hunan Univ, Changsha, Hunan 410082, China
Abstract:Temperature profile and shear rate were used to optimize the processing conditions to develop laminar morphology in blow molding high density polyethylene(HDPE)/polyamide(PA6) blends. The result showed that it was good to form laminar morphology of dispersed phase PA6 in proper temperature profile and lower shear rate. It also showed drat blow molded botdes with laminar blend of HDPE and PA6 reduced greatly in permeability, compared with the bottles made from HDPE. For example, the barrier properties to arene increased 40 times. Meanwhile, their mechanical strength was as good as those made from HDPE.
Keywords:polyethylene  polyamide  laminar mixing  barrier properties  blow molding
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