| 超声萃取—高效液相色谱测定沉积物中的多环芳烃 |
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| 引用本文： | 冯精兰,申君慧,翟梦晓,孙剑辉. 超声萃取—高效液相色谱测定沉积物中的多环芳烃[J]. 河南师范大学学报(自然科学版), 2011, 39(6): 88-91 |
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| 作者姓名： | 冯精兰 申君慧 翟梦晓 孙剑辉 |
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| 作者单位： | 河南师范大学化学与环境科学学院,河南省环境污染控制重点实验室,河南新乡453007 |
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| 基金项目： | 河南省重点科技攻关项目，河南省教育厅自然科学基础研究计划，河南省基础与前沿研究计划 |
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| 摘 要： | 用正己烷—丙酮(1∶1,体积比)混合液作溶剂,超声萃取提取沉积物中的16种多环芳烃组分.萃取液经硅胶小柱层析净化,旋转蒸发仪浓缩,最后用高效液相色谱—荧光串联紫外检测器分析,并进行加标回收测定.16种多环芳烃的检测限为0.34～1.52 ng· g-1,经精密度试验,相对标准偏差均＜15％,回收率在57.09％～103...
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| 关 键 词： | 超声萃取 高效液相色谱 荧光检测器 紫外检测器 多环芳烃 沉积物 |
Determination of Polycyclic Aromatic Hydrocarbons in Sediment Using Sonicate Extraction-high Performance Liquid Chromatography |
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| FENG Jing-lan,SHEN Jun-hui,ZHAI Meng-xiao,SUN Jian-hui. Determination of Polycyclic Aromatic Hydrocarbons in Sediment Using Sonicate Extraction-high Performance Liquid Chromatography[J]. Journal of Henan Normal University(Natural Science), 2011, 39(6): 88-91 |
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| Authors: | FENG Jing-lan SHEN Jun-hui ZHAI Meng-xiao SUN Jian-hui |
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| Affiliation: | (College of Chemistry and Environmental Sciences,Henan Normal University,Henan Key Laboratory for Environmental Pollution Control,Xinxiang 453007,China) |
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| Abstract: | Sonicate extraction has been used to extract 16 polycyclic aromatic hydrocarbons in sediments with acetone: n-hexane(1∶1) mixed solvent.After the purification process by a silica gel column,the solution is passed to high performance liquid chromatography-fluorescent detector-ultraviolet detector for analysis.Standard addition recovery rate is determined with quartz sand as substrate.Standard addition recovery rate is performed over 16 polycyclic aromatic hydrocarbons with the detection limit ranging from 0.34 ng·g-1 to 1.52 ng·g-1,while in precision testing the relative standard deviationswas below 15% with recovery rate staying between 57.09% and 103.41%. |
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| Keywords: | sonicate extraction HPLC,fluorescent detector ultraviolet detector polycyclic aromatic hydrocarbons sediment |
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