The reaction of acenaphthene with nitrobenzene |
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| Authors: | Wu Lin Li Hong Chen Shao-feng Qin Yi-min Zong Zhi-ming Wei Xian-yong Zou Guo-lin |
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| Affiliation: | (1) College of Life Sciences, Wuhan University, 430072 Wuhan, Hubei, China;(2) Department of Biology and Chemistry, Chongqing College of Education, 400067 Chongqing, China;(3) College of Chemical Engineering, China University of Mining & Technology, 221008 Xuzhou, Jiangsu, China |
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| Abstract: | The reaction of acenaphthene with nitrobenzene was investigated in the presence of AlCl3. The results showed that the reaction proceeded via carboncation-electrophilic substitution reaction and free radical substitution reaction pathway. The products of acenaphthenyl phenylamine and biacenaphthyl could be synthesized by this reaction. The influence of the amount of AlCl3 and the temperature on the components of products were also studied in this reaction. Foundation item: Supported by the National Nature Science Foundation of China (No. 29676045) Biography: Wu Lin (1965-), male, Postdictor, research direction: PAHs catalytic conversion and its biologic toxicity. |
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| Keywords: | acenaphthene nitrobenzene carboncation free radical reaction mechanism acenaphthenyl phenylamine biacenaphthyl |
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