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辉光放电等离子体引发制备丙烯酸酯类高吸油树脂及其性能研究
引用本文:高锦章,李兴发,李岩,马得莉,杨武. 辉光放电等离子体引发制备丙烯酸酯类高吸油树脂及其性能研究[J]. 西北师范大学学报(自然科学版), 2011, 47(2): 59-63
作者姓名:高锦章  李兴发  李岩  马得莉  杨武
作者单位:西北师范大学化学化工学院;
基金项目:教育部重点科技基金资助项目(00250); 甘肃省自然科学基金资助项目(3ZS041-A25-028096RJ2A120); 西北师范大学科技创新工程资助项目(NWNU-KJCXGC-01)
摘    要:用辉光放电等离子体引发悬浮聚合法制备了丙烯酸酯类高吸油树脂,用衰减全反射傅里叶变换红外光谱(ATR-FTIR)、热重分析(TGA)和扫描电镜(SEM)对产品的结构、热稳定性和表面形貌进行了表征,对放电参数、交联剂的量进行了考察和讨论,同时研究了吸油速率和吸油动力学.结果表明,此法制备的高吸油树脂具有较高的吸油倍率和较快...

关 键 词:辉光放电等离子体  高吸油树脂  聚丙烯酸酯  动力学

Synthesis and characterization of a highly oil-absorptive resin by using glow-discharge electrolysis plasma
GAO Jin-zhang,LI Xing-fa,LI Yan,MA De-li,YANG Wu. Synthesis and characterization of a highly oil-absorptive resin by using glow-discharge electrolysis plasma[J]. Journal of Northwest Normal University Natural Science (Bimonthly), 2011, 47(2): 59-63
Authors:GAO Jin-zhang  LI Xing-fa  LI Yan  MA De-li  YANG Wu
Affiliation:GAO Jin-zhang,LI Xing-fa,LI Yan,MA De-li,YANG Wu (College of Chemistry and Chemical Engineering,Northwest Normal University,Lanzhou 730070,Gansu,China)
Abstract:A highly oil-absorptive resin,poly(butyl acrylate),is prepared by suspension polymerization,which is initiated by glow-discharge electrolysis plasma(GDEP).The structure is characterized by means of attenuated total reflectance Fourier transform infrared spectroscopy(ATR-FTIR),thermogravimetric analysis(TGA) and scanning electron microscopy(SEM).The effects of the discharge voltage,discharge time and the amount of the crosslinking agent on the oil absorbency are examined and discussed in detail.The oil absor...
Keywords:glow-discharge electrolysis plasma(GDEP)  highly oil-absorptive resin  polycbutyl acrylate  kinetics  
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