| 高聚物含双核配体键联钌络合物催化剂的制备及其催化加氢活性 |
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| 引用本文： | 赵维君,王玲,张书笈,方延铨. 高聚物含双核配体键联钌络合物催化剂的制备及其催化加氢活性[J]. 应用科学学报, 1992, 0(1) |
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| 作者姓名： | 赵维君 王玲 张书笈 方延铨 |
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| 作者单位： | 南开大学(赵维君，王玲，张书笈)，南开大学(方延铨) |
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| 摘 要： | 以氯甲基化聚苯乙烯-二乙烯基苯树脂为载体,分别制得含氮-磷、氮-氮、氮-氧双核配体的功能高分子,这些功能高分子化学键联三氯化钌获得固载化催化剂,应用于二丙酮醇加氢反应,具有较高的活性和选择性.
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| 关 键 词： | 双核配体 络合催化剂 固载化催化剂 加氢反应 钌 |
CATALYST PRERATION OF POLYMER BOUND RUTHENIUM (III) COMPLEXES CONTAINING BINUCLEAR LIGANDS AND ACTIVITY OF CATALYTIC HYDROGENATION |
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| ZHAO WEIJTJN WANG LING ZHANG SHTJJI FANG YANQUAN. CATALYST PRERATION OF POLYMER BOUND RUTHENIUM (III) COMPLEXES CONTAINING BINUCLEAR LIGANDS AND ACTIVITY OF CATALYTIC HYDROGENATION[J]. Journal of Applied Sciences, 1992, 0(1) |
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| Authors: | ZHAO WEIJTJN WANG LING ZHANG SHTJJI FANG YANQUAN |
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| Affiliation: | Naikai University |
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| Abstract: | With ohloromethylated polystyrene divinylbenzene as a support, the funotionalizened polymers containing N-P, N-0, or N-N binuelear ligand were pi-epared. These functionalized polymers were chemically bound with RuOls forming supported catalysts. Used in the hydrogenation of Diketo-alcohol the catalysts displayed high activity and selectivity. |
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| Keywords: | binuolear liganda complex catalyst supported catalyst hydrogenation reaction ruthenium. |
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